6.1.1: Optical Isomerism Flashcards
Which form isomerism is optical isomerism
stereoisomerism
Stereoisomerism
Stereoisomers have the same structural formula but a different arrangement of atoms in space.
Chiral carbon atom
A carbon atom with four different groups attached to it.
Chiral also known as
asymmetric
Optical isomers
Two molecules with a different arrangement of groups around the chiral carbon atom which are mirror images.
Enantiomers
optical isomers
Enantiomers can’t be?
superimposed
Achiral
molecules that can be superimposed
Plane polarised light
Normal light that has been passed through a polarising filter which means that all light vibrates in the same plane.
Optical isomers are…
optically active
Optical isomers effect on plane polarised light
Rotate the plane of the light, 2 enantiomers rotate plane polarised light in opposite directions, clockwise and anticlockwise.
Racemate also known as
racemic mixture
Racemate
Contains equal quantities of each enantiomer of an optically active compound and don’t show any optical activity
Reacting two achiral products can produce…
a racemic mixture of a chiral product
Why do two enantiomers cancel out each other’s light rotating effect?
When two molecules react, there is equal chance of forming each of the enantiomers