6.1.2: Aldehydes and Ketones Flashcards
What type of compounds are aldehydes and ketones?
carbonyl compounds
Carbonyl functional group
C=O
Difference between aldehydes and ketones?
The position of their functional group
Aldehydes
Have their C=O group at the end of the carbon chain
Ketones
Have their C=O group at the middle of the carbon chain
Aldehydes suffix
-al
Ketones suffix
-one
Aldehydes can be oxidised to
carboxylic acids
Why aren’t ketones easily oxidised
have to break a c-c bond
Two reagents used to distinguish between aldehydes and ketones
Tollens’ reagent
Fehling’s solution
Tollens’ reagent
Silver nitrate dissolved in aqueous ammonia
colourless
Tollens’ reagent test
Heat tollens’ reagent with an aldehyde to produce a silver mirror (precipitate)
Fehling’s solution
Blue solution of complexed copper (II) ions dissolved in NaOH
Fehling’s solution
Heat with an aldehyde to produce a brick-red precipitate
Reducing agent for reduction of aldehydes and ketones
NaBH4