12.2 Pressure Law Flashcards
What relationship does the pressure law describe?
Relationship between pressure and temperature
What is the relationship between pressure and temperature
They’re directly proportional
What has to be fixed to analyse pressure and temperature?
Volume and mass
What does a graph of pressure against temperature look like? if temperature is in kelvin
Straight line through the origin.
What is the pressure law numerically?
p = kt p/t = k
What does the graph of pressure against temperature look like? if temperature is in celsius
Straight line starting from -273 at x axis
Why does temperature increase with pressure>?
Higher temperature means molecules gain kinetic energy, so that they move faster. If the volume stays constant then molecules collide more often and at higher speed so pressure will increase.
What are the rules for working with this relationship? in terms of calculations
- p is the TOTAL pressure
- T must be in Kelvin
Equation for pressure law?
p1/t1 = p2/t2
Why is this the equation?
As they both equal k, the constant hence they must be equal to each other as long as mass and volume are kept constant
What setup would we use to investigate the pressure law?
A beaker placed in cold water. A thermometer in water, gas in beaker and a tube from beaker leading to pressure gauge. There is also a heating source
What is one thing we have to make sure is done about tube connecting beaker to pressure gauge?
It is as short and as thinnest as possible. This is because volume inside needs to be reduced to minimum as air will not be the same temperature as in the flask.
Describe this practical?
Initially the water is made cold by putting ice into it in order to get the lowest staring temperature. The pressure and corresponding temperature are recorded up to the boiling point of water. Time must be given to allow air in beaker to reach temperature of water (done by turning the heating down). Also the water is stirred throughout to allow equal distribution of temperature.
At zero pressure and hence volume we get what?
Absolute zero