Unit 6 - Lesson 1 Maturation & Blending Flashcards
What benefits of maturation?
Reduces harshness
Adds color
Adds sweet flavor
What are the 3 reactions that take place in maturation?
- Additive
- Subtractive
- Sensory
What is an additive reaction?
Compounds are extracted from the wood into the spirit for
1. Flavor & 2. Color
Does wood have many flavor compounds?
Not relative to the raw materials and yeast
What is an example of a flavor compound?
Vanillin - additive flavor smells of vanilla and increases perceived sweetness during maturation
What are key factors for flavor and color?
Type of Cask
Storage Conditions
What are subtractive reactions?
When flavor compounds are removed or reduced
What are 3 types of subtractive reactions?
- Evaporate
- Removed - Interaction with wood eg char and sulphur
- Transformation eg reactions with other components in spirits like oxidation
What evaporates in casks?
Casks are not airtight - angle share
volatile compounds
water
alcohol
What impact does char have?
It creates a subtractive reaction and reduces sulphur compounds leaving flavor compounds unchanged hence reduces harshness
What does oxidation do to spirits?
Is a subtractive reaction when O2 reacts with flavor compounds
What are sensory Interactions?
It is perceived change of flavor even though level of compounds has not changed.
Change detected by senses
How would cereal-reduction provide a sensory interaction?
Cereal aromas reduce over time since other flavor compounds have developed during maturation
What are the factors that influence maturation?
- Cask and its construction
- How the spirit is treated prior to the cask
- Storage conditions
What are the considerations for selecting wood casks?
- Must be pliable
- Long lengths
- Free from defects (no knots)
- Not too porous
What are the main flavor components for oak?
Oak lactones - coconut aromas
Tannins - bitterness and astringency
What is Quercus alba?
American Oak
What is Quercus robur?
European Oak
What is Quercus Mongolica?
Japanese Oak
What happens to a cask once it is built and why?
Heat treated - a step to generate flavor
Heat breaks down structural components of oak
What does heat treatment do to oak?
Breaks down Lignin
Increases the additive flavor compounds
Otherwise there is only Oak Lactones and Tannins
What is Lignin?
Main structural component of oak
IN cell walls and gives rigidity
Highly branched molecule
What does heat do to Lignin?
Breaks down the highly complex molecule into smaller ones and some of these are flavor compounds
What are the main flavor compounds of heat treated oak?
- Vanillin - vanilla
- Eugenol - spicy, clove
- 4-ethyl guaiacol - smoke, spicy
What are the 2 types of heat treatment for wood?
Toasting & Charing
What is toasting?
heat the surface of the cask without igniting the wood
What is charring?
Igniting the inside of the casks for a period to build a layer of char
What does the char layer have in a cask?
Contains little or no additive flavor compounds since most burned off in charing process. Wood below char has the flavor compounds