Types and Effects of Intermolecular Forces Flashcards

1
Q

Intramolecular forces? 3 types?

A

forces WITHIN a molecule itself that keep a molecule together. 1) Metallic, 2) Ion-Ion, and 3)
covalent network

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2
Q

Intermolecular forces?

A

Are forces that keep one molecule sticking to another molecule. The stronger the force, the more intensely molecules are attracted to each other

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3
Q

4 types of intermolecular forces?

A

1) ion-dipole
2) hydrogen bonding
3) dipole-dipole
4) dispersion forces (Van der Waals)

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4
Q

Ion-dipole Intermolecular force

A

intermolecularforce between ions and polar substances (NaCl in water)

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5
Q

hydrogen bonding intermolecular force

A

N-H, F-H, O-H bond in a pure substance

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6
Q

Dipole-dipole intermolecular force?

A

intermolecular force between POLAR non-ionic molecules that do NOT have an H bonded to O, N, or F

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7
Q

Dispersion Forces (or called London or van der Waals forces)

A

this is the intermolecular force between all molecules. Temporary dipole includes polar and nonpolar molecules. The greater the weight, the greater the London dispersion forces

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8
Q

list dipole-dipole, dispersion forces, and hydrogen bonding in order of increasing strength?

A

dispersion forces, dipole-dipole, hydrogen bonding, and ion-dipole

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9
Q

Can dispersion forces occur in individual atoms as well?

A

yes

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10
Q

If you have two molecules that only have dispersion forces, how do you know which one has more forces?

A

The larger molecule

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11
Q

If you have two molecules that only have dispersion forces, which one has a higher boiling point?

A

The larger molecule, bc the stronger the intermolecular force the higher the boiling point

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12
Q

All molecules have what type of intermolecular force?

A

dispersion forces

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13
Q

What is the weakest intermolecular force?

A

dispersion forces

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14
Q

strong IM forces indicate 4 properties?

A

1) high boiling point (high heat of vaporization)
2) high viscosity
3) high surface tension
4) low vapor pressure

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15
Q

viscosity

A

how thick a substance is. The thicker a substance, the more slowly it pours.
Ex: molasses is more viscous than water

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16
Q

vapor pressure

A

upward pressure exerted by a substance on the atmosphere (or against atmospheric pressure)

17
Q

When does boiling occur?

A

when the vapor pressure of a liquid substance equals or exceeds atmospheric pressure

18
Q

IM forces and vapor pressure are directly or indirectly related?

A

indirectly

19
Q

Would water boil faster on top of a mountain or in the grand canyon?

A

Top of a mountain. Bc atmospheric pressure decreases with higher altitude causing a lower boiling point

20
Q

Why would vapor pressure decrease as boiling point increases?

A

If something has a high boiling point. that means it has a low vapor pressure bc it requires MORE HEAT to makes the vapor pressure high enough to allow boiling

21
Q

what is atmospheric pressure at sea level?

A

1 atm. BP of water at sea level is 100 degrees C

22
Q

Vapor pressure and boiling point are related how?

A

indirectly. higher vapor pressure=lower BP