Topic 1—A: Biological molecules- 4. lipids Flashcards
what are lipids commonly known as?
fats or oils
how are lipids different from carbohydrates and proteins?
they aren’t polymers formed from long chains of monomers
what are lipids made from?
they are made from a variety of different components
- they all contain hydrocarbons
what are hydrocarbons?
molecules that contain only hydrogen and carbon atoms
what are the two types of lipids?
triglycerides
phospholipids
triglycerides structure
- they have 1 molecule of glycerol
- 3 fatty acids attached to it
- fatty acid molecules have long ‘tails’ of hydrocarbons
- tails are hydrophobic so they repel water molecules which make lipids insoluble in water.
fatty acids (structure)
- consist of the same basic structure
- hydrocarbon tail varies
- they have a carbon atom that links fatty acid to glycerol
- Variable ‘R’ group hydrocarbon tail
- Carboxyl group (COOH)
O
C-R
/
HO
what are the three kinds of fatty acids and the main difference?
saturated, unsaturated and polyunsaturated
Difference is in their hydrocarbon tails (R groups)
Saturated fatty acids
- Don’t have any double bonds between their carbon atoms (no c=c bond)
- The fatty acid is saturated with hydrogen
- Form straight chains and have high melting points
Unsaturated fatty acids
- Do have double bonds between carbon atoms (c=c bond)
- Cause the chain to kink
- Form bent chains and have low melting points
Polyunsaturated fatty acids
- More than 1 double bond between carbon atoms (more than 1 c=c bond)
Triglycerides (glycerol)
H
I
H-C-OH- Fatty acid
I
H-C-OH- Fatty acid
I
H-C-OH- Fatty acid
I
H
3 carbon groups
3 hydroxl groups
How are triglycerides formed?
- Formed by condensation reactions
- Fatty acids join to a glycerol molecule (at the OH) (Hydroxl part)
- As 3 fatty acids joins to 3 different OH groups, 3 condensation reactions are happening so 3 molecules of water are produced.
- An ester bond forms between the 2 molecules (the OH of the glycerol and HO of the fatty acid) which releases a molecule of water.
Phospholipid (structure)
- They have one molecule of glycerol
- 2 fatty acids attached to it (Hydrocarbon tail)
- 1 phosphate group
- Glycerol and fatty acids are connected by an ester bond
- Phosphate group is hydrophilic (attracts water) (heads face outwards towards the water on either side)
- Fatty acid tails are hydrophobic (repels water)
- Centre of bilayer is hydrophobic so water-soluble substances can’t pass through it. (acts as a barrier)
Emulsion test (lipids)
- Add ethanol to a test substance
- Shake test substance with ethanol for about 1 minute
- Add distilled water and shake
- Any lipid will show up as a white milky emulsion (more lipid there is the more noticeable the milky colour will be)