Thermochemistry Flashcards
______ and ______ are not state functions
Work and Q (heat)
+ w = work done ___ system
- w = work done ___ system
+ w = on
- w = by
(chem = add-on/subtract by)
Which follow isochoric conditions
Isochoric conditions means w = 0
Solids liquids and sealed gases
so Q = ∆E
∆Hcombustion is always
Exothermic
Order of negativity in standard states ∆H
Solid then liquid then gas (so if gas is standard state then liq and sol states are neg)
∆Hneutralization is always
Exothermic
∆Hatomization is always
Endothermic
Molar specific heat capacity will always be ____ than specific heat capacity
Greater than
Calorimeter
Device used to measure standard enthalpy
Spontaneous reactions
Burning of coal
Neutralization
Evaporation
When ∆H = q
when ∆E = q
∆H = q means constant p
∆E = q means constant v (eevie)
G —> L —> S is
Exothermic (Exo is gls (jealous))
SI unit of specific heat capacity
J g-1 K-1
Strong acid/base kJ
-57.5 kJ
Anything less is a weak acid/base