Gases Flashcards
1 atm all other values
76 cm Hg
760 mm Hg
760 torr
101325 Ns
101325 Pa
101.325 kPa
1 Bar
14.7 Psi
Ideal gas laws
Negligible volume
Equally sized particles, no IMF
Move randomly
Perfectly elastic collisions (no energy loss)
Boyle’s Law
PV
V proportional to 1/P
Charles’ Law
V proportional to T
V = kt
Zero Kelvin is the temp at which
All motions of ideal gases are ceased
Ideal gas equation in density terms
PV = dRT so
d = [PM/RT]
Value of R at atm dm^3 mol-1 K-1
0.0821
Value of R at mmHg dm^3 mol-1 K-1
62.4
Value of R in torr cm-3 mol-1 K-1
62400
Value of R in Nm mol-1 K-1
8.314
Value of R in J mol-1 K-1
8.314
Value of R in cal mol-1 K-1
1.97
SI unit of gas constant
Nm mol-1 K-1
z =
PV / nRT
z = 1 ideal
z= 1.2 non ideal
z = 0.8 non ideal
When are gases non ideal
High pressure and low temp
HP LT = non ideal (HP Legacy is Trash)