Solids Flashcards

1
Q

Viscosity of solids

A

Infinite

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2
Q

Amorphous solids has _____ MP/BP

A

Long range

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3
Q

Another name for amorphous solids

A

Supercooled liquids

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4
Q

Examples of amorphous solids

A

Plastic, wood, glass, rubber, gemstone, concrete, polymer

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5
Q

Crystalline solids have particles arranged

A

In 3D

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6
Q

Crystalline solids cleavage plane

A

Proper (anisotropic)

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7
Q

Crystalline solids other name

A

True solids

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8
Q

Crystalline solids examples

A

NaCl, KI, diamond, graphite, ice, dry ice, CaCO3, MgO, Fe, Cu, K, Mg, Sr

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9
Q

How many elements of symmetry

A

23

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10
Q

Cubical solids

A

NaCl, diamond, MgO, NaF

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11
Q

Hexagonal solids

A

Graphite, Water (ice), ZnO, CdS

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12
Q

Orthorhombic solids

A

KNO3, AgNO3

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13
Q

Isomorphs are

A

Solids that have the same structure (cubical etc)
(So NaCl and diamonds are isomorphs)

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14
Q

Polymorph is

A

One solid that has many structures
(KNO3 and AgNO3 can be orthorhombic and rhombahedral)
(CaCO3 can be trigonal and orthorhombic)

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15
Q

Polymorphs have

A

Similar chemical properties but different physical properties

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16
Q

Isomorphs have

A

Same structure, same ratio of combined elements
Different physical and chemical structures

17
Q

Allotrophy is

A

When one element can exist as different forms
(C = diamond / graphite)
(S = Sd / Sp)
(Sn = Sn white / Sn grey)

18
Q

Allotrophy has

A

Same chemical properties
Different physical properties

19
Q

Transition temp is

A

Temp at which 2 crystalline forms can coexist

20
Q

Transition temp of Sn grey / Sn white

A

13.2º

21
Q

Transition temp of Sa / Sp

A

95.5º

22
Q

Transition temp of KNO3 (orhtorhombic) / KNO3 (rhombohedral)

A

128.6º

23
Q

Growth of crystals (How to get large size)

A

Slow growth = Large size
If vapor used = Large

24
Q

Impurities in crystalline

A

Pure NaCl = cubical
Small impurities = Flat crystals
5-10% urea = needle shaped crystals

25
Q

Examples of molecular solids are

A

CO2 (solid) (dry ice) / sugar crystals / naphthalene / urea / Cl2 / O2 (s) / N2 (s) / Br2 (s)

26
Q

Simple cube coordination number

A

6

27
Q

Body centered cube coordination number

A

8

28
Q

Face centered cube coordinate number

A

12

29
Q

Low temperature = ______ Stable

A

More

30
Q

Cubic crystallographic element

A

a = b = c = equal length
a = ß = ¥ = 90º

31
Q

Trigonal crystallographic elements

A

a = b ≠ c
a = ß = ¥ = 90º

32
Q

Hexagonal crystallographic elements

A

a = b ≠ c
a = ß = 90º ¥ = 120º

33
Q

Rhombohedral crystallographic elements

A

a = b = c
a = ß = ¥ ≠ 90º

34
Q

Orthorhombic crystallographic elements

A

a ≠ b ≠ c
a = ß = ¥ = 90º

35
Q

Monoclinic crystallographic elements

A

a ≠ b ≠ c
a = ¥ = 90º ß ≠ 90º

36
Q

Triclinic crystallographic elements

A

a ≠ b ≠ c
a ≠ ß ≠¥