The halogens (Gr 7) - ES Flashcards

1
Q

What does fluorine look like at room temp

A

colourless gas

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2
Q

What does chlorine look like at room temp

A

pale green gas

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3
Q

What does bromine look like at room temp

A

brown liquid

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4
Q

What does iodine look like at room temp

A

silver/black solid

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5
Q

What trends happens down the halogens

A

colour gets darker, melting point and boiling point increase : they are less volatile and switch from gas to liquid to solid as intermolecular bonds get stronger

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6
Q

Halogens solublity

A

they are not very soluble in water but much mores soluble in organic solvents

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7
Q

Halogens as elements characteristics

A

they exist as diamotic molecules, they are in the p-block on the periodic table and outer shell for all is s²p⁵

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8
Q

Chemical properties of halogens

A

to achieve noble gas configuration a halogen atoms has to gain one electrons which means they are oxidising agents. Oxidising power increases going up the group

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9
Q

How is oxidising power affects up the group of halogens

A

it increases because the incoming electron is closer and less shielded from the positive nucleus so attraction is stronger

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10
Q

Halogens with metals

A

the halogens form an ionic compound. They fully gain an extra electron, becoming halide ions

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11
Q

Halogens with non-metals

A

the halogens share electrons, forming a covalent bond

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12
Q

Cl⁻ colour

A

colourless

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13
Q

Br⁻ colour

A

colourless

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14
Q

I⁻ colour

A

colourless

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15
Q

Cl₂ in aqueous solution colour

A

very pale green

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16
Q

Br₂ in aqueous solution colour

A

orange

17
Q

I₂ in aqueous solution colour

A

brown

18
Q

Cl₂ in organic solvents colour

A

pale green

19
Q

Br₂ in organic solvents colour

A

brown

20
Q

I₂ in organic solvents colour

A

purple

21
Q

A halogen higher in the group is ale to …

A

oxidise (react with) the halide ion of a halogen lower in the group

22
Q

How to see clearly the colour difference in halogens

A

an organic solvent is added and the mixture is shaken, the organic solvent and water do not mic so 2 layers form. Halogen molecules are non-polar so dissolve better in the upper, organic layer (also non-polar) giving it a characteristic colour which is more distinctive to see

23
Q

Tests for halides in solution

A

add silver nitrate (AgNO) and then to check shake with aqueous ammonia solution

24
Q

Fl⁻ and AgNO observation + formula + ionic equation

A

no precipitate

25
Q

Cl⁻ and AgNO observation + formula + ionic equation

A

white precipitation, AgCl (silver chloride)
Ag⁺ + Cl⁻ -> AgCl

26
Q

Br⁻ and AgNO observation + formula + ionic equation

A

cream precipitation, AgBr (silver bromide)
Ag⁺ + Br⁻ -> AgBr

27
Q

I⁻ and AgNO observation + formula + ionic equation

A

yellow precipitation, AgI (silver iodide)
Ag⁺ + I⁻ -> AgI

28
Q

What happens to silver halides when left in the sun

A

they start to go grey/black due to formation of silver as they are light sensitive

29
Q

What happens when AgCl is shaken with aqueous ammonia solution

A

completely redissolves

30
Q

What happens when AgBr is shaken with aqueous ammonia solution

A

partially redissolves

31
Q

What happens when AgI is shaken with aqueous ammonia solution

A

does not redissolve

32
Q

Risks of using chlorine

A

very toxic and any leak can be dangerous as it is a gas so will spread quickly

33
Q

Uses of chlorine

A

water treatment (drinking and pools) to kill germs, make household bleach, extract bromine from sea water, make HCl