Chemical equilibrium - ES Flashcards
Equilibrium definition
when the rate of the reverse reaction is equal to the rate of the forward reaction, it is then at dynamic equilibrium
Features of equilibrium
forwards and reverse reactions are both happening, but at the same rate, so the concentration of each substance is staying constant. Can only happen in a closed system
What happens to the equilibrium when there aren’t equal concentration of reactions and products
the equilibrium position can be to the right (more products) or to the left (more reactants)
Graph of when more reactants are produced at equilibrium
https://www.siyavula.com/read/za/physical-sciences/grade-12/chemical-equilibrium/images/764b1c1dce0bfcba7f7ced47ae70771c.png
RHS
Graph of when more products are produced at equilibrium
https://www.siyavula.com/read/za/physical-sciences/grade-12/chemical-equilibrium/images/764b1c1dce0bfcba7f7ced47ae70771c.png
LHS
Le Chateliers principle
if a reaction is at equilibrium and then a change is made in any of the conditions (Temp, Pressure, Conc) then the position of equilibrium will shift in the direction that minimises the change
Changing the pressure at equilibrium
increasing pressure shifts the equilibrium in the direction with fewest gas molecules
decreasing pressure would shift the equilibrium to the side with the most gas molecules
Changing the temperature at equilibrium
increasing the temperature shifts the equilibrium position in the endothermic direction (this takes in heat, reducing the temperature, so minimising change)
decreasing the temperature would shift the equilibrium position in the exothermic direction
Changing the concentration at equilibrium
If one of the reactants conc increases the equilibrium position would shift to the right, minimising the change
If one of the reactants conc decreases the equilibrium position would shift to the left, minimising the change
If one of the products conc increases the equilibrium position would shift to the left, minimising the change
If one of the products conc decreases the equilibrium position would shift to the right, minimising the change
Adding a catalyst at equilibrium
a catalyst does not change the position of equilibrium as a catalyst speeds up the rate of both the forward and reverse reaction equally. But it will reach equilibrium quicker