TB 86 - Structural Fumigations and Other Pesticides Flashcards
What is the chemical responders will MOST LIKELY encounter at a fumigation incident?
Sulfuryl fluoride
(sulfuryl fluoride is currently used in over 95% of all fumigations throughout the United States.)
What are the 3 most widely used chemicals in fumigation?
-Sulfuryl fluoride (MOST USED)
-Chloropicrin (warning agent similar to tear gas)
-Aluminum phosphide (used in ships, trains, aircraft, grain silos, ect. where TENT fumigation is IMPRACTICAL)
(Methyl bromide was widely used, however is now ONLY USED to fumigate AGRICULTURE FIELDS in Cali. Mainly strawberries)
What are the 4 brand names you can encounter that use sulfuryl fluoride?
-Vikane (structural fumigant)
-MasterFume
-Profume (agricultural fumigant)
-Zythor
Because sulfuryl fluoride is odorless, it will always be used with the warning agent __________.
-chloropicrin (tear gas with strong odor)
(small chloropicrin soaked rags are placed in the structure on protective plates similar to pie tins PRIOR to the introduction of the sulfuryl fluoride.)
_________ is used where tent/tarp fumigations are impractical. When exposed to air, the water in the air REACTS with the TABLETS to create the fumigant gas, PHOSPHINE.
-Aluminum Phosphide
Consider the following at incidents involving aluminum phosphides:
• Request a full HAZMAT assignment
• DO NOT use WATER on incidents involving spilled tablets
• Residual spent tablet dust DOES NOT present a hazard
• Fires in shipping containers undergoing fumigation MAY be extinguished with water, however, consideration to the increased release of poisonous gas
• AVOID the use of WATER in fires involving BULK quantities of tablets as it could cause a MAJOR VAPOR CLOUD
• There are NO manufacturers or warehouses of tablets in the City of Los Angeles
The most common trade names of Aluminum Phosphides are:
-CelPHOS
-FumiTOXIN
-PhosTOXIN
-Talunex
-Quick PHOS.
Pesticides can be inhaled, ingested, and/or absorbed through the skin. All pesticides encountered in the _____ form should be treated as if they are SKIN ABSORPTIVE.
When in the ________ state, sulfuryl fluoride and chloropicrin ARE NOT skin absorptive.
-Liquid form
-gaseous
Aluminum Phosphide gives off what kind of odor when it is releasing its fumigant gas?
Garlic
The company conducting the fumigation will have warning signs with the following information:
-TYPE of fumigant used
-WHEN it was applied
-NAME of fumigation COMPANY
-24 hour emergency CONTACT NUMBER
Appropriate PPEs shall be worn for all personnel working within _____ feet of the structure involving fumigation.
This includes when to go “on air” with the SCBA.
30 ft
What is the appropriate PPEs that shall be worn at structures involving fumigation?
• Full turnouts
• SCBA with facepiece, donned and on air.
Additionally, all personnel performing rescue or rapid extraction operations shall wear the following:
• Nitrile EMS gloves WITH EITHER firefighting gloves OR the GREEN nitrile over-gloves from the HazMat bag as the OUTER GLOVE.
Any incident involving SKIN ABSORPTIVE fumigants, LIQUID pesticides, pesticides in INDUSTRIAL CONCENTRATIONS or any leak or spill involving storage, transport or dissemination vessel requires a full _______ Assignment.
HazMat Assignment
Fumigation Incidents
The following resource request shall be made through MFC if not dispatched or on scene:
• LAFD HazMat Task Force and Squad
• PM Rescue
• LF or Truck for use of blowers
• Joint Hazard Assessment Team (JHAT), through MFC.
• LAPD HazMat, if crime is suspected.
The following notifications shall be made at ALL fumigation incidents:
• The fumigation company, as soon as possible
• The LA County Department of Food and Agriculture.
Suspected burglaries are the responsibility of LAW ENFORCEMENT but a homeless person seeking shelter or a someone potentially impaired or incapacitated by poisonous fumigant becomes a rescue problem for LAFD personnel.
Therefore, a ________ must be performed to determine whether Fire or Police will take the lead for the initial entry.
-threat assessment
(IN ALL CIRCUMSTANCES Fire Department personnel SHALL establish a Unified Command with Law Enforcement and co-locate at the CP.)