Stereoisomers Flashcards
Define stereoisomers
The number of possible stereoisomers of a carbohydrate is determined by what?
By the formula of the number of asymmetric carbon atoms
What are the types of isomerism
D and L isomerism
Optical isomers
Epimers
Diastereoisomers
Aldo-keto isomers
Anomers
Define D and L isomerism
The D and L forms of sugar are mirror images of each other, with reversed configurations at the penultimate carbon
What will be the OH position for the D and L isomerism
D sugars are what?
Naturally occurring sugars and the body can metabolize only D sugars
Explain optical isomers
Explain epimers
Two sugars that differ from one another only in configuration around a single Carbon atom
Give examples of epimers
Glucose and galactose - C4
Glucose and mannose - C2
Explain diastereoisomers
What’s the difference between diastereomers and enantiomers ?
Diastereomers have different physical properties, like melting and boiling point, solubility, and they do not rotate plane-polarized light in equal but opposite directions
Explain the Aldo - keto isomers
Explain Anomers
D glucose is what
Dextrorotatory
D fructose is what
Levorotatory