Rates of Reaction + Factors Affecting + Catalysts Flashcards

1
Q

Describe the collision theory

A

the only way for chemical reactions to take place is if the reactant particles collide with sufficient amount of energy to react

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2
Q

Successful Collision -

A

a collision that leads to a reaction as particles have E >Ea

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3
Q

2 main Factors the rate of chemical reactions depend on

A
  1. Collision Frequency of reacting particles - how many collision between particles in a certain amount of time
    - more collisions = faster the reaction (because more successful collision)
  2. Amount of energy particles have : more energy = more energy transferred during collision
    - more successful collisions
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4
Q

Name 4 Factors the affect the rate of reaction

A
  • temperature
  • concentration of solution / pressure of gas
  • surface area
  • presence of a catalyst
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5
Q

How does temperature affect the rate of reaction?

A
  • Heat = particle have more energy
  • move faster
  • more frequent collisions
  • higher temperature = increase energy of the collisions —> particles are faster+ more particles with E>Ea
  • more successful collisions
  • rate increases
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6
Q

How does concentration (solutions) / Pressure (gas) affect the rate of reaction?

A

-higher collision frequency
- More particles in a given volume
- More frequent collisions, more crowded
- more successful collsions
rate increases

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7
Q

How does having a smaller solid particle (surface area) affect the rate of reaction?

A
  • More particles exposed: increase its surface area to volume ratio
  • more frequent collsions -> particles have more area to work on
  • more successful collisions
  • rate increases
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8
Q

How does a catalyst work and how does it affect the rate of reaction?

A
  • provides an alternative reaction pathway for reaction with a lower activation energy
  • more particles have at least the minimum amount of energy (activation energy) needed for particles to collide
  • more successful collisions as more particles with E>Ea
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9
Q

What is a catalyst

A
  • substance that increases the rate of a chemical reaction cwithout being chemically changed or used up
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10
Q

Rate of reaction equation =

A

Rate of reaction = Amount of reactant used or amount of product formed (cm^3)/ Time(s)

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11
Q

What is Activation energy and why is it needed for a reaction?

A
  • minimum amount of energy particles need to react with
  • particles need this much energy to break the bonds in reactants to start reaction
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12
Q

What happens to the energy needed if the activation energy is greater? How will it be supplied

A

greater the activation energy = more energy needed to start reaction
- need to be Supplied, e.g. heating the reaction mixture

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13
Q

What are reaction profiles used for?

A

To compare the activation energy of a reaction with and without a catalyst

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14
Q

Is the highest point on the curve on a reaction graph with or without a catalyst

A

Highest point = with catalyst
Lower = without catalyst

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