Covalent Bonding + Substances Flashcards
What are the 2 types of covalent bonds?
- Simple Molecular
- Giant Covalent
Definition of simple molecular structure
Very strong Covalent bonds between ATOMS within the molecule.
- Weak intermolecular forces between MOLECULES
What are covalent bonds made from
Non-metals + non-metals
Do simple molecular substances had high/low melting and boiling point?
LOW
- Weak Intermolecular forces
- require little energy to break
What is the effect on the melting and boiling point when the relative molecular mass increases in a simple molecular substance
- Melting + boiling point INCREASE
- higher relative molecular mass = more intermolecular forces = more energy needed to break
Are covalent substances conductors?
DO NOT CONDUCT
- no free moving charged particles
- EXCEPT GRAPHITE: has delocalised electrons that can flow
Which 3 covalent substances have giant covalent lattice structures
Diamond, Silicon, Graphite
Definition of giant covalent lattices
electrostatic attraction between the pairs of shared electrons and the nuclei of the bonded atoms
Do giant covalent lattice substances have a high/low melting and boiling point?
VERY HIGH
- Strong covalent bond
- require a lot of energy to break
Do giant covalent lattice structures conduct electricity?
DO NOT CONDUCT - not free moving charged particles
EXCEPT GRAPHITE- does have free flowing delocalised electrons
Are giant covalent lattice structures hard or malleable?
Very hard, EXCPET GRAPHITE
- graphite - layers can Slide Over each other
- layers are on held by weak intermolecular forces
- graphite is soft and slippery
what type of atom are diamond and graphite made out of
Carbon atoms
Describe the properties and structure of atoms in a diamond
- each carbon atom covalently bonded to 4 other carbon atoms
- very strong covalent bonds: Lots of energy needed to break, very high melting point
- strong covalent bonds hold atoms in a very rigid lattice structure
- does NOT CONDUCT electricity: no free electrons/ions
Describe the structure of atoms in graphite
- each carbon atom covalently bonded to 3 other carbon atoms
- creates layers of carbon atoms
- layers held weakly by intermolecular forces
- layers free to slide over eachother: soft and slippery
- used as lubricant
Can graphite conduct electricity and why?
YES
- only 3 out of each carbons 4 electrons are used in bonds
- each carbon has one free delocalised electron that can move and conduct
What is the structure of Fullerene (C60)
Simple molecular
Hollow sphere, made up of 60 carbon atoms
Does fullerene have a high/low melting point?
LOW
- weak intermolecular forces
- needs little energy to break
Is fullerene hard or soft?
Soft
- only held by intermolecular forces
- can Slide Over each other
is fullerene a electrical conductor?
Poor electrical conductor
- each carbon in fullerene has one delocalised electron
- electron cant move between molecules, cant conduct well
Why can graphite conduct electricity?
- only 3 out of each carbon’s 4 outer electrons are used in bonds
- each carbons has ONE electrons the is delocalised and and move freely
- graphite is a non-metal that conducts electricity
Does graphite have a high/low melting point and why?
HIGH melting point
- covalent bonds in the layers need LOTS of ENERGY to break