Quantum Mechanics Flashcards

1
Q

3 basic ideas of QUANTUM MECHANICS

A
  1. atoms/molecules ONLY EXIST at certain energy states
  2. there is CHANGE in ENERGY upon absorption and emission of light
  3. the ALLOWED ENERGY STATES are described by QUANTUM NUMBERS
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2
Q

definition of ORBITAL (2)

A
  • REGION in atom where e- is most probable
  • described by n, l, and ml
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3
Q

maximum # of e- that a region can hold

A

2

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4
Q

QUANTUM NUMBERS

MAIN energy level/shell of e- (radius lines around nucleus)

A

principle qn (n)

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5
Q

QUANTUM NUMBERS

describes the size of an orbital

A

principle qn (n)

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6
Q

QUANTUM NUMBERS

takes integer value starting from 1

A

principle qn (n)

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7
Q

QUANTUM NUMBERS

subshells

A

azimuthal qn (l)

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8
Q

QUANTUM NUMBERS

describes shape of an orbital

A

azimuthal qn (l)

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9
Q

QUANTUM NUMBERS

the s, p, d, f orbitals

A

azimuthal qn (l)

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10
Q

QUANTUM NUMBERS

has values 0 to n-1

A

azimuthal qn (l)

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11
Q

find the subshell for the respective azimuthal values:

l = 0
l = 1
l = 2
l = 3

A

s
p
d
f

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12
Q

how many orbitals per subshell?

A

s = 1
p = 3
d = 5
f = 7

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13
Q

QUANTUM NUMBERS

spatial orientation

A

magnetic qn (ml)

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14
Q

QUANTUM NUMBERS

covers # of degenerate (same energy) orbitals per subshell

A

magnetic qn (ml)

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15
Q

QUANTUM NUMBERS

has values from -l to +l

A

magnetic qn (ml)

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16
Q

QUANTUM NUMBERS

electron spin

A

spin qn (ms)

17
Q

define ELECTRONIC CONFIGURATION

A

arrangement of e- in ground state

18
Q

3 principles in ELECTRONIC CONFIGURATION

“Building-up” Principle

A

Aufbau

19
Q

3 principles in ELECTRONIC CONFIGURATION

orbitals are filled w increasing energy

A

Aufbau

20
Q

3 principles in ELECTRONIC CONFIGURATION

determined by the (n + l) rule

A

Aufbau

21
Q

3 principles in ELECTRONIC CONFIGURATION

degenerate orbitals are FIRST singly occupied

A

Hund’s Rule of Multiplicity

22
Q

3 principles in ELECTRONIC CONFIGURATION

unpaired e- must have parallel spins

A

Hund’s rule of multiplicity

23
Q

3 principles in ELECTRONIC CONFIGURATION

no two e- have the same quantum #

A

Paul’s exclusion