experiment 3-4 concepts Flashcards

1
Q

molecules in solid and liquid states are held together by ______________ forces

A

intermolecular forces

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2
Q

2 general types of intermolecular forces

A
  1. London Dispersion Forces
  2. Dipole-dipole Forces
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3
Q

Forces found in NON-POLAR MOLECULES and POLAR MOLECULES

A

NPM - LDF

PM - DDF and LDF

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4
Q

Special type of DDF

A

Hydrogen Bonding

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5
Q

In hydrogen boding, what is attached to H

A

O, N, F

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6
Q

what is the energy needed to increase the surface area of a liquid by one unit

A

Surface Tension

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7
Q

Unbalanced/Balanced IMFA in the surface of liquids cause surface tensions

A

Unbalanced

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8
Q

Unbalanced/Balanced IMFA causes surface tension

A

Unbalanced

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9
Q

Effect of IMFA on Melting and Freezing Point

A

Stronger = Higher

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10
Q

What type of net force do IMFA create on surface of liquids

A

Inward Net Force

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11
Q

Effect of IMFA on Melting/Freezing Point

A

Stronger IMFA = High MP and FP

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12
Q

What states exist in equilibrium at Melting and Freezing Point temperatures

A

solid and liquid

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13
Q

What must be supplied to solids to turn into liquid and why

A

ENERGY - break IMFA

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14
Q

What will be used to determine the ff:

  1. Melting Point
  2. Freezing Point
A
  1. Melting Point Determination Apparatus
  2. Cooling Curve
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15
Q

Relationship of KE and Temperature in Freezing

A

Direct Relationship

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16
Q

What is PE in Freezing

A

Stored Energy in Chemical Bonds

17
Q

What are COLLIGATIVE PROPERTIES

A

DEPENDS on molarity of solute present (not on nature)

18
Q

Freezing Point Lowering Formula

A

T solvent - T solution = kf m

where:
Tfo = freezing point of the pure solvent
Tf = freezing point of solution
kf = freezing point depression constant of the solvent
m = molality of the solution

19
Q

Molality formula

A

m = T solvent - T solution / kf

20
Q

Molar Mass Solute formula

A

MM = [(mass solute)(kf) / (T solvent - T solution)(kg solvent)]

21
Q

Molarity VS Molality

A

Molarity = moles solute / Liter solution

Molality = moles solute / kg solvent

22
Q

“Arrest” VS “Break” Temperature

A

A: plateau during phase change

B: downward slope after phase change

23
Q

Downward slope and Plateau Description (KE and PE)

A

DS: KE decreases, PE constant
CS: PE decreases, KE constant

24
Q

Sensible vs Latent Heat

A

S: energy required to change the temperature of the substance with no phase change.

L: energy absorbed or released by a substance during phase change

25
Q

3 cooling curve variations

A
  1. no distinct plateu
  2. no distinct plateu

get average of first and last point right before downward slopw

26
Q

Reason for Cooling Curve 1 and 2

A

Impurities interrupt the organized crystal packing during solidification

27
Q

Two general types of IMFA

and what do you collectively call these 2

A

London Dispersion Forces
dipole-dipole forces

van der Waals forces

28
Q

compounds ending with -one contains what type of bonding

A

no hydrogen bonding