Bonding and Structure of Organic Compounds Flashcards

1
Q

4 main ERAS in the history of organic chemistry

A
  1. 1700s History
  2. Theory of Vitalism
  3. Against Vitalism
  4. Structural Theory
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2
Q

1700s HISTORY (2)

  • Year
  • Scientist
  • Event
A

MID-1700s
- living (blood & synthesized sugar) and non-living substances (natural sugar & minerals) were discovered

1700s
- Torbern Bergman (differentiated the 2 substances)

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3
Q

Theory of Vitalism (1)

  • Year
  • Scientist
  • Event
A

1810
- Jons Jacob Berzelius

  • coined the term “organic”
  • said that organic compounds CAN ONLY be synthesized by living matter due to VITAL FORCE
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4
Q

Against Vitalism (3)

  • Year
  • Scientist
  • Event
A

1816
- Michel-Eugene Chevrul
- made FATTY ACIDS from soap (non-living matter)… soap is made from animal fats

1828
- Friedrich Wohler
- “Father of Organic Chemistry”
- synthesis of UREA from ammonium cyanate (first org synthesis)

1860
- Marcelin Berthelot
- synthesis of organic compounds from C H O N

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5
Q

Structural Theory (7)

  • Year
  • Scientist
  • Event
A

1858 & 1861
- Friedrich Kekule
- Archibald Couper
- Alexander Butlerov
- Tetravalency of Carbon & basis for STRUCTURAL THEORY

1862
- Emil Fischer
- triple bond in acetylene

1864
- Alexander Brown
- double bond in ethylene

1869
- Wilhelm Korner
- structures of benzenes

1872
- Viktor Meyer
- steric hindrance in organic compounds

1916
- Gilbert Lewis
- explained the nature of covalent compounds

1926
- Erwin Schrodinger
- Werner Heisenberg
- Paul Dirac
- advancement in ATOMIC and MOLECULAR STRUCTURE

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6
Q

STRUCTURAL THEORY

  • main definition
A

“in org chem, atoms form a fixed # of bonds”

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7
Q

ORGANIC COMPOUNDS

_______ compounds
consists of mainly what type of atom
what type of bond

A

chemical compounds
with CARBON atoms
covalent bonds

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8
Q

Common misconception about ORGANIC MATERIALS

A

organic materials STILL contain chemicals tho it is widely believed to be purely made of living matter

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9
Q

2 TYPES OF ORGANIC COMPOUNDS

  1. Natural
    - definition (2)
    - example (3)
  2. Synthetic
    - definition (1)
A
  1. Natural
    - derived from living things
    - isolated from living matter in a laboratory
    + biomolecules
    + phytochemicals
    + secondary metabolites
  2. Synthetic
    - made from scratch in a laboratory
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10
Q

2 main properties of CARBON

A
  1. Tetravalency
  2. Catenation
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11
Q

TETRAVALENCY

  • How many bonds
  • What type of bonds
  • With what type of atoms
A
  • Four bonds
  • Covalent bonds
  • All atoms (including carbon)
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12
Q

CATENATION

  • ability to__?
  • what does catenation result to?
A
  • ability to form bonds with carbon atoms
  • to form chains
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13
Q

3 TYPES of backbone that CARBON can form:

A
  1. Linear
  2. Branched
  3. Cyclic
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14
Q

3 TYPES of bonds that CARBON can form:

A
  1. Single
  2. Double
  3. Triple
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15
Q

Who are the TWO (2) authors that proposed tetravalency?

A
  1. Friedrich August Kekule
  2. Archibald Scott Couper
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16
Q

OTHER 5 characteristics of CARBON in terms of:

  1. melting point
  2. solubility
  3. state in room temp
  4. combustibility
  5. sensitivity to ___?
A
  1. LOW mp
  2. LIMITED (no) solubility in water
  3. MOST are liquid; SOME are gas
  4. combustible
  5. sensitive to heat
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17
Q

2 TYPES of structural formula

A
  1. Expanded
  2. Condensed
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18
Q

Condensed Formula VS Skeletal Formula

A

CF
- shows condensed elements into molecules

SF
- a “line-angle” structure

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19
Q

SKELETAL FORMULA

how to draw the ff:
1. Carbon Atoms
2. Hydrogen Atoms
3. Other Atoms

A
  1. not drawn (depicted in line ends/bends)
  2. not drawn IF ATTACHED to a carbon atom
  3. always drawn
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20
Q

ISOMERS

  • 2 types
  • Where the WORD came from (2)
A
  1. Structural
  2. Stereoisomers
  • ISO = equal ; MER = part
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21
Q

STRUCTURAL ISOMERS (2) VS STEREOISOMERS (1)

A

Structural
- same molecular formula
- different structural formula

Stereo
- differ in orientation of atoms in space

22
Q

Other term for structural isomers

A

Constitutional Isomers

23
Q

If 2 compounds have different structural formulas despite having the same molecular formula, are they still considered as the same compound?

24
Q

3 TYPES of Structural Isomers

A
  1. Skeletal
  2. Functional Group
  3. Positional
25
Q

3 TYPES of Structural Isomers

SKELETAL ISOMER

same….
different….

A

same functional group
different carbon skeleton

26
Q

3 TYPES of Structural Isomers

FUNCTIONAL GROUP ISOMERS

________ isomers
different…….

A

constitutional isomers
different functional groups

27
Q

3 TYPES of Structural Isomers

POSITIONAL ISOMERS

______ isomers
same….
same….
different…

A

constitutional isomers
same carbon skeleton
same functional group
different location

28
Q

DIFFERENTIATE BETWEEN:

  1. Same compounds
  2. Different compounds and not isomers
  3. Different compounds that are constitutional isomers
A
  1. Same # of C
    Same carbon structure
  2. Different # of C
    May be same # of C but different # of bonds
  3. Same # of C
    Different carbon structure
29
Q

Index of Hydrogen Deficiency FORMULA

A

IHD =

2C + 2 + N - H - X
/
2

X = halogens

30
Q

Index of Hydrogen Deficiency OTHER TERM

A

Degree of Unsaturation

31
Q

3 RULES in IHD

A
  1. Double Bond / Ring = 1 IHD
  2. Triple Bond = 2 IHD
  3. Always a positive integer
32
Q

Bond angle present in the ff:

  • Linear
  • Trigonal Planar
  • Tetrahedral
A

180

120

109.5

*if with lone pairs, bond angles will change acc since stronger repulsion

33
Q

LEWIS vs KEKULE structures

and which of the 2 is more used in organic compounds

A

L: electron-dot structures
K: line-bond structures

KEKULA more used

34
Q

Are bond strength significant in resonance structures?

A

NO,, if yung changing of bonds yung affected per individual resonance structure

35
Q

5 rules on RESONANCE STRUCTURES

A
  1. individual resonance structures are imaginary
  2. only pi bonds and non-bonding e- can move around
  3. resonance forms dont have to be equivalent
  4. must be valid lewis structures
  5. the RESONANCE HYBRID is the TRUE STRUCTURE of molecules
36
Q

In benzene rings, how is RESONANCE STABILITY symbolized?

A

Arrow na paikot sa loob ng ring

37
Q

FUNCTIONAL GROUPS

  • main function
  • 2 characteristics
A

classify organic compounds REGARDLESS OF size and complexity

  1. definite arrangement
  2. characteristic chemical behaviour
38
Q

“Class of Organic Compound”

  • definition
A
  • group of compounds containing the same functional group
39
Q

Recite all FUNCTIONAL GROUPS

HYDROCARBONS (4)
HETEROATOMS (18)

A

hydrocarbons - hydrogen and carbon only

heteroatoms - other elements

40
Q

AROMATIC RING, key features (2)

A
  1. has a ring
  2. all atoms forming the ring are connected to a double bond (OR there are 3 double bonds in strucuture)
41
Q

4 rules in CONDENSED formulas

A
  1. central atoms and those connected to it are written in a group
  2. carbons in linear backbone are written together
  3. functional group written as one
  4. double and triple bonds are always shown
42
Q

WHICH ARE MORE STABLE?

compounds vs individual atoms

43
Q

Common BONDING PATTERNS of the following elements:

  1. Carbon
  2. Hydrogen
  3. Nitrogen
  4. Oxygen
  5. Halogens
A

CARBON - 4

NITROGEN - 3

OXYGEN - 2

HYDROGEN - 1

HALOGEN - 1

44
Q

2 theories that explain SHARING OF ELECTRONS

  • main difference (process of formation)
A

COVALENT BONDS ARE FORMED FROM:

  1. Valence Bond Theory - the overlap of atomic orbitals (each with opposite electron spins)
  2. Molecular Orbital Theory (a mathematical combination of atomic orbitals to form a new set of orbitals: MOLECULAR ORBITAL)
45
Q

In VALENCE BOND THEORY:

  • relationship between AMOUNT OF ORBIT OVERLAP and STRENGHT OF BOND
A

DIRECT

greater overlap = greater strength

46
Q

ANTIBONDING vs BONDING molecular orbitals

  • what interacts?
  • presence of electron density
A

BONDING
- like phases interact
- increases electron density between nuclei

ANTIBONDING
- opposite phases interact
- no electron density between nuclei

47
Q

ORBITAL HYBRIDIZATION

  • proposed by?
  • when
  • main definition
  • explains what?
A
  • Linus Pauling (1931)
  • mathematical mixing of orbitals that are close in energy to generate a set of equivalent HYBRID ORBITALS
  • explains the valence bond treatment of bonding in organic molecule with the tetravalent carbon IN RELATION TO GEOMTERY
48
Q

4 CONSIDERATIONS in writing structures

A
  1. Valency of Atoms
  2. Possible functional groups
  3. Isomerism
  4. Degree of hydrogen deficiency
49
Q

IMPORTANT REMINDER for connecting carbon atoms with bonds

A

Sa carbon dapat didikit

50
Q

EXAMPLE of HALOGENS

A

F, Cl, Br, I, At, Ts