experiment 5 Flashcards

1
Q

3 factors that affect rate of chemical reaction

A

concentration of reactants, temperature, and presence of catalyst

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2
Q

what (explain process) dictates the speed of reactions

A

how reactants OVERCOME energy barriers (ACTIVATION ENERGY)

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3
Q

how can the concentration effect be better understood

A

rate law expressions

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4
Q

____ dictates how changes in one reactant will affect the conversion to product

A

order of reaction

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5
Q

method to obtain the order with respect to a reactant

A

Method of initial rates

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6
Q

2 criteria for a chemical reaction to occur

A
  1. must be in proper orientation
  2. must have enough energy to overcome activation energy
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7
Q

What reacting species are included in writing rate law expressions?

A

Only reactants

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8
Q

How to get the total reaction order?

A

Sum of all individual reaction orders

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9
Q

Effect of increasing the ff on rate of reaction

  1. Concentration
  2. Temperature
  3. Addition of Catalyst
A

Increase rate of reaction

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10
Q

in the reaction:

Rate = [A] ^ m [B] ^ n

How to get the experimental order in terms of A?

A
  1. Cross out [B] ^ n
  2. Matitira is:
    rate 1 / rate 2 = [A1] ^ m / [A2] ^ m
  3. to get m order:

m = [log (rate1 / rate2)] / [log (A1 / A2)]

same thing with n order

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11
Q

How to get the rate constant

A

K = rate / ([A]^m [B]^n)

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12
Q

What are the units of the RATE CONSTANT per order?8

A

0th order = M/s
1st order = 1/s
2nd order = M^-1 s^-1
3rd order = M^-2 s^-1
4th order = M^-3 s^-1

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