Intermolecular Forces Flashcards
Intramolecular forces vs Intermolecular forces
which is STRONGER
intramolecular (between atoms)
BOND TYPES arrangement based on strength
- Ionic
- Covalent
- Metallic
IMFAs arrangement based on strength
- Ion-ion
- Ion-dipole
- Hydrogen Bonding
- Dipole-dipole
- London dispersion
what DEVELOPS in London Dispersion Forces
INDUCED DIPOLE - temporary, instantaneous dipole
what IMFA is present in all molecules
LDF
what IMFA is the ONLY one present in NOBLE GASES
LDF
relationship of the ff with LDF
- atomic radius
- molar mass
- surface area
DIRECT: for all
atomic radius: at bigger atoms, valence e- are less attracted to nucleus thus can form induced dipoles more easily
surface area: more linear-» more area exposed
Polarizability DEFINITION
tendency of atom to acquire an induced dipole
what among the 2 types of intermolecular interactions DOMINATES in dipole-dipole forces?
and which of these do liquids experience and why?
attractive intermolecular interactions over repulsive
both because they are free and continuous
which IMFA contain partial charges due to permanent dipole
Dipole-dipole forces
H + what
to attain hydrogen bonding
N, O, F and to some extent S and Cl
what IMFA is formed from the combination of short dipole-dipole moments and large bond dipoles
hydrogen bonding
Requirements for H-bonding sites
O, N, F
or
H attached to above
STRONGER IMFA PRIORITIZATION
of H bonding sites > H bonding > molar mass > polarity
NONPOLAR rules
- Monoatomic
- C + H