Intermolecular Forces Flashcards

1
Q

Intramolecular forces vs Intermolecular forces

which is STRONGER

A

intramolecular (between atoms)

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2
Q

BOND TYPES arrangement based on strength

A
  1. Ionic
  2. Covalent
  3. Metallic
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3
Q

IMFAs arrangement based on strength

A
  1. Ion-ion
  2. Ion-dipole
  3. Hydrogen Bonding
  4. Dipole-dipole
  5. London dispersion
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4
Q

what DEVELOPS in London Dispersion Forces

A

INDUCED DIPOLE - temporary, instantaneous dipole

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5
Q

what IMFA is present in all molecules

A

LDF

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6
Q

what IMFA is the ONLY one present in NOBLE GASES

A

LDF

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7
Q

relationship of the ff with LDF

  1. atomic radius
  2. molar mass
  3. surface area
A

DIRECT: for all

atomic radius: at bigger atoms, valence e- are less attracted to nucleus thus can form induced dipoles more easily

surface area: more linear-» more area exposed

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8
Q

Polarizability DEFINITION

A

tendency of atom to acquire an induced dipole

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9
Q

what among the 2 types of intermolecular interactions DOMINATES in dipole-dipole forces?

and which of these do liquids experience and why?

A

attractive intermolecular interactions over repulsive

both because they are free and continuous

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10
Q

which IMFA contain partial charges due to permanent dipole

A

Dipole-dipole forces

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11
Q

H + what

to attain hydrogen bonding

A

N, O, F and to some extent S and Cl

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12
Q

what IMFA is formed from the combination of short dipole-dipole moments and large bond dipoles

A

hydrogen bonding

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13
Q

Requirements for H-bonding sites

A

O, N, F

or

H attached to above

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14
Q

STRONGER IMFA PRIORITIZATION

A

of H bonding sites > H bonding > molar mass > polarity

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15
Q

NONPOLAR rules

A
  1. Monoatomic
  2. C + H
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16
Q

POLAR RULES

A

H + N, O, F

17
Q

palatandaan sa chemicals ending with -one

A

NO hydrogen bonding