O Chem 2 Test 5 Flashcards
amine
a cmpd which can be thought of as an ammonia derivative, with one or more H’s replaced by R groups
common names for 1 degree amines
naming the r group, the adding amine
IUPAC names for one degree amines
naming the amino group as a substituent
CA names for 1 degree amines
naming as an alkanamine
primary amine
ammonia with 1 H replaced by R
secondary amine
ammonia with 2 H’s replaced by R groups
IUPAC names for 2 degree amines
naming the NH entity as amino with the smaller R group as part of the amino function and the larger R group as base name
CA names
naming as an alkanamine with the smaller R group as part of an “N” function positioned on the larger R group
tertiary amine
ammonia with all 3 h’s replaced by r groups, not necessarily the same
Ca names for 3 degree amines
naming as an alkanamine with the smaller R groups as part of an “N,N” function positioned on the larger R group
Alkylation
substituting an alkyl group into the structure of a molecule
amide
a cmpd with an N bonded to a carbonyl
nitrile
an organic cmpd containing the cyanide group
aryldiazonium ion
Ar-N2+
diazotization
the process of making aryldiazniumions
diazonio group
N2+ on an arromatic ring
benzenediazonium ion
benzene ring-N2+
sandmeyer reaction
conversion of aryldiazonium ion to aryl chlorides, bromides, or cyanides
azo dyes
cmpds formed by linking an aryldiazonium ion with a strongly activated aromatic ring
diazo coupling
the reaction forming an azo dye by linking an aryldiazonium ion with an aniline or phenol derivative
azo group
the N=N entity linking the 2 reactants in diazo coupling
amino acid
a cmpd containing an amine function & an organic acid function
hydrolysis
forcing water into a molecular structure to break the structure into smaller units
alpha amino acids
a.a.’s with the amine function on the alpha carbon
