Mono and Polysaccharides MCDB108 A Flashcards

1
Q

sugars are metabolic _______ in energy conversion pathways

A

intermediates

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2
Q

energy storage molecules are _____ and _____

A

starch, glycogen

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3
Q

glycocalyx is a sugary coat that is partly _______ and partly ____

A

structural, signaling

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4
Q

chitin and cellulose provide _______ support

A

structural

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5
Q

sugars are common post translational modifications on proteins for _____, _____ and _____

A

signaling, stability, trafficking

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6
Q

there is no ______ code for sugars, it is specifed by variable __.

A

genetic, enzymes

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7
Q

monosaccharides have _____ carbon centers and are ______ active

A

chiral, optically

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8
Q

monosaccharides are ______ and can ______ by the nucleophilic _____ attacking the electrophilic _____

A

reactive, cyclize, hydroxyl, carbonyl

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9
Q

in cells sugars are found in their _______ form

A

cyclic

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10
Q

right side in fischer projection means ________ in haworth

A

down

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11
Q

pyranoses prefer _____ structure, furanose prefer ____

A

chair, envelope

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12
Q

monosaccharides are linked into poly by _______ bonds

A

glycosidic

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13
Q

reactions with alcohols form _________ bond

A

o glycosidic

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14
Q

reactions with amines from ______ bond

A

n glycosidic

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15
Q

monosaccharides polymerize through ________ bonds through a ______ reaction

A

o glycosidic, condensation

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16
Q

in the condensation reaction the _______ at the anomeric carbon attacks OH on another sugar and releases _____ to form the polysaccharide

A

hemi acetal, water

17
Q

saccharides with hemiacetals are __________ sugars

A

reducing

18
Q

one to one means _______ are linked

A

anomeric carbons

19
Q

starch and glycogen are glucose polymers with primarly ______ linkages

A

alpha 1-4

20
Q

amylose is _______ alpha 1-4

A

linear

21
Q

amylopectin is the same as amylose but _______ branch points

A

alpha 1-6

22
Q

glycogen is like starch but has more ____ branch points

A

alpha 1-6

23
Q

amylose can form a _______ with ___ glucose per turn stabilized by h bonds

A

helix, six

24
Q

advantages of alpha 1-6 crosslinking means there are many ________ ends, and have compact ______ without changing osmolarity

A

nonreducing, storage

25
Q

metabolic enzymes mobilize glycogen from ________ end

A

nonreducing

26
Q

reducing end is nonspecifically _______

A

reactive

27
Q

structural polysacs can have __________ properties with _______ components

A

different, same

28
Q

cellulose is found in ______ walls with _____ linkages. it allows tight packing, h bonding and excludes water.

A

plant, beta 1-4

29
Q

the same properties that govern protein _______ dictate polysacchride structure

A

folding

30
Q

properties of anomeric carbon and addition of side groups will make some conformations ________ than others generating long range order

A

more stable