Exam 2 Flashcards
Which of the following represents kinetic energy?
a. The flow of hydrogen ions (H+) through ATP synthase and the phosphorylation of ADP to form ATP
b. A concentration gradient across a membrane
c. An electric charge imbalance across a membrane
d. Both A and B
e. All of the above
A
The sum total of all the anabolic and catabolic reactions in a living cell is called its
a. energetics.
b. activity.
c. metabolism.
d. entropy.
e. respiration.
C
Which term most precisely describes the cellular process of making higher energy molecules out of lower energy ones?
a. catalysis
b. metabolism
c. anabolism
d. condensation
e. catabolism
C
How does the first law of thermodynamics apply to organisms?
a. As energy transformations occur, free energy is transferred from one form to another, it is neither created nor destroyed.
b. To maintain order, life requires a balance of energy.
c. The potential energy of ATP is converted to kinetic energy such as muscle contractions but also releases heat.
d. Reactions occur only with a release of energy.
e. It does not apply to organisms; the complexity of organisms contradicts the first law.
A
During photosynthesis, plants capture only about 5% of the energy available in sunlight and convert it into the potential energy found in glucose. This inefficiency in energy transfer is an example of?
a. negative free energy (-ΔG).
b. chemical equilibrium.
c. the first law of thermodynamics.
d. the second law of thermodynamics.
e. a spontaneous reaction.
D
In any system, the total energy includes usable and unusable energy. The usable energy is referred to as
a. free energy.
b. entropy.
c. heat.
d. thermodynamics.
e. equilibrium.
A
If ΔG of a chemical reaction is positive, you can conclude that it…
a. releases energy.
b. is endergonic.
c. is exergonic.
d. will not reach equilibrium.
e. increases the disorder in the system.
B
The mathematical expression for the free change in free energy of a system is ΔG=ΔH-T ΔS. Which of the following is (are) correct?
a. ΔS is the change in entropy
b. ΔH is the change in free energy
c. ΔG is a change in the enthalpy
d. T is the temperature
e. Answers A and D are correct
E
Which of the following statements about enzymes is false?
a. An enzyme changes shape when it binds to a substrate.
b. Enzymes lower the activation energy.
c. Enzymes can only catalyze a certain number of reactions before they are completely consumed.
d. An enzyme may orient substrates, induce strain, or temporarily add chemical groups.
e. Most enzymes are much larger than their substrates.
C
The hydrolysis of sucrose to glucose and fructose is exergonic. However, if sucrose is dissolved in water and the solution is kept overnight at room temperature, there is no detectable conversion to glucose and fructose. Why?
a. The change in free energy of the reaction is positive.
b. Room temperature does not achieve the necessary energy of activation for the reaction to occur.
c. The change in free energy of the reaction is negative.
d. This is a condensation reaction.
e. The free energy of the products is higher than the free energy of the reactants.
B
In some cases, a substrate–enzyme complex is stabilized by
a. hydrogen bonds.
b. covalent bonds.
c. ionic attractions.
d. hydrophobic interactions.
e. all of the above
E
Which of the following could denature an enzyme?
a. high temperature
b. changes in pH.
c. an allosteric regulator
d. answers A and B are correct
e. all of the above are correct
D
Why is ATP an important molecule in metabolism?
a. Its hydrolysis provides an input of free energy for endergonic reactions.
b. Its terminal phosphate groups ionize easily, releasing free energy.
c. It transfers (couples) free energy between exergonic and endergonic reactions.
d. Answers A and B are correct
e. All of the above are correct
E
Many enzymes require NAD+ and NADH for a reaction to occur. They temporarily bind to and then release from the substrate to participate in other reactions. NAD+ and NADH are considered
a. a side chain.
b. a coupled reaction
c. coenzymes
d. a prosthetic group.
e. cofactors.
C
Four atoms of ferrous Iron (Fe) are required for hemoglobin protein to efficiently carry oxygen in the human bloodstream. The iron most likely functions as a(n)
a. cofactor necessary for enzyme activity
b. noncompetitive inhibitor of the enzyme.
c. allosteric activator of the enzyme.
d. competitive inhibitor of the enzyme.
e. coenzyme necessary for moving hydrogen ions from one pathway to another.
A
How do competitive and noncompetitive enzyme inhibitors differ?
a. They function at different pH values.
b. Competitive inhibitors have a higher energy of activation than noncompetitive inhibitors have.
c. Competitive inhibitors bind to the active site, whereas noncompetitive inhibitors change the shape of the active site.
d. Noncompetitive enzyme inhibitors contain magnesium, whereas competitive inhibitors contain iron.
e. Noncompetitive enzyme inhibitors are reversible, whereas competitive inhibitors are irreversible.
C
An allosteric inhibitor
a. decreases the concentration of the enzyme.
b. changes the shape of a substrate.
c. increases the concentration of a product.
d. changes the shape of an enzyme (the shape of its active site).
e. increases the concentration of an enzyme–substrate complex.
D
The process that involves an end product acting as an inhibitor of an earlier step in a metabolic pathway is called
a. feedback inhibition.
b. feedback activation.
c. positive feedback.
d. concerted activation.
e. competitive inhibition.
A
When organisms move from one environment to another, they sometimes synthesize variations of existing enzymes, which are called
a. coenzymes.
b. isozymes.
c. abzymes.
d. effectors.
e. activators.
B
Consider the pathway below, if product F is an allosteric inhibitor of enzyme 3, what will be the result as F accumulates?
a. The concentration of product C will decrease.
b. The concentration of reactants A and B will increase.
c. The concentration of product E will increase because more of F is converted back to E.
d. The concentration of product D will increase.
e. The concentration of products E and F will both increase.
D