Enthalpy Change Flashcards

1
Q

What is enthalpy change?

A

The amount of heat energy transferred during a chemical reaction at a constant pressure.

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2
Q

units for ΔH

A

Kj mol-1

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3
Q

What are the standard conditions?

A

100kPa and 298K

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4
Q

Exothermic

A

gives out energy

ΔH is negative

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5
Q

Give an example of exothermic reaction:

A
  1. combustion of methane
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6
Q

Endothermic reactions

A

Absorb energy
ΔH is positive

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7
Q

What reaction is bond breaking?

A

endothermic- you need energy to break bonds

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8
Q

What reaction is once the bonds are formed?

A

Exothermic as energy is released.

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9
Q

What is bond enthalpy?

A

Bond enthalpy is the energy required to break bonds.

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10
Q

Define standard enthalpy of formation

A

the enthalpy change when 1 mole of a compound is formed from its elements in their standard state under standard conditions.

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11
Q

Define standard enthalpy of combustion.

A

the enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions.

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12
Q

Define specific heat capacity

A

The amount of energy required to raise the temperature of 1g by 1k.

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13
Q

If the surroundings have a lower specific heat capacity what happened

A

An exothermic reaction will cause a bigger increase in the temperature of the surroundings

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14
Q

What are the units for specific heat capacity

A

Jk-1g-1

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15
Q

Equation for enthalpy change

A

Q= mcAt

Q- amount of heat energy given out or taken in (J)
M- mass of the surrounding (g)
c- specific heat capacity

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16
Q

If the reaction is exothermic

A

We add a negative sign at the front

17
Q

If the reaction is endothermic

A

Add a + sign to the front

18
Q

Simple flame calorimetry

A

Burn water using a flame.
Measure the temperature change of the water

19
Q

What are some problems with the simple flame calorimeter

A

Some of the energy will be lost.e.g the water will give off vapours into the air.
To prevent this, increase the mass of the water but this can cause such a small change in temperature.

20
Q

How do you find the molar enthalpy?

A

Divide the enthalpy change by the moles

21
Q

What element are found as gases under standard state?

A

Nitrogen
oxygen
chlorine
fluorine
hydrogen
And all noble gases

22
Q

What elements are found as liquid under their standard state?

A

Bromine and mercury

23
Q

If an element is under standard state what is their enthalpy change?

A

Always zero!

24
Q

When a metal reacts with oxygen, what will it form?

A

Metal+ oxgyen——> metal oxide

25
Q

Define enthalpy of combustion

A

The standard enthalpy of combustion is when one mole of a substance is fully burned in oxygen under standard conditions with all reactants and products under their standard state

26
Q

Define Hess’s law

A

The enthalpy change in a reaction at constant pressure is independent of the route taken

27
Q

Arrows for enthalpy of formation

A

The both face upwards so arrow one needs to be flipped

28
Q

How is an exothermic reaction shown from a thermometer?

A

A rise in temperature

29
Q

How is a endothermic reaction shown by a thermometer?

A

Temperature drops