EL8 + EL9 Flashcards
trends in s-block elements
more metallic/reactive down a group, more readily form cations in ionic compounds
less metallic/reactive across a period
soft, weak metals with low MPs
too reactive with water and oxygen to have many uses
form very useful and important compounds
1st ionisation enthalpy
energy required to remove one electron from every atom in one mole of isolated, gaseous atoms of the element
as you go across a period, 1st ionisation enthalpy
increases
more difficult to remove an electron
more electrons in the outer shell but also more protons being added to the nucleus, so electrons held more tightly
as you go down a group, 1st ionisation enthalpy
decreases
attraction between nucleus and outermost electrons decreases
more filled electrons between nucleus and outer shell shielding charge of nucleus
trends in group 2 elements and compounds - reactivity with water
reactivity increases down group
due to shielding effect of electron shells
trends in group 2 elements and compounds - thermal decomposition
becomes more difficult as you descend the group
more reactive elements at bottom of group prefer to be in compounds
trends in group 2 elements and compounds - lattice enthalpy (endothermic)
as you descend the group, less energy is required to break bonds that hold the ions in a lattice together because interatomic distances are greater
trends in group 2 elements and compounds - hydration enthalpy of ions (exothermic)
as you descend group, less energy is released from hydration of cation
trends in group 2 elements and compounds - strength and solubility of oxides + hydroxides
stronger and more soluble at bottom of group
trends in group 2 elements and compounds - strength and solubility of carbonates
stronger and more soluble at top of group
acid
a compound that dissociates in water to produce protons
base
compound that reacts with acids by accepting protons to produce water and a salt
alkali
base that dissolves in water to produce hydroxide ions
oxonium ion
when an acid is in a solution of water, a H3O+ ion forms