DF5 Flashcards
Cracking
any reaction in which a large molecule is made into smaller molecules
Reasons for cracking
to meet the demand of petrol, to get other desirable chemicals eg. alkenes
Unsaturated
a compound not containing the maximum number of hydrogen because it contains double/triple bonds
Catalyst
increases the rate of chemical reaction but can be recovered chemically unchanged at the end
Physical changes of a catalyst
may sometimes be changed physically, eg. solid catalyst begins to crumble, this suggests the catalyst is taking part in the reaction but is being regenerated
Homogeneous catalysis
when the reactant and catalyst are in the same physical state
Heterogeneous catalysis
when the catalyst and reactant are in different physical states
Heterogeneous catalysis; process
reactants are adsorbed onto the catalyst surface,
bonds are weakened,
bonds break and new bonds form,
product diffuses away from catalyst surface leaving it free to adsorb fresh reactants
Poisoned catalysts; process
poison molecules are adsorbed strongly to the catalyst surface,
catalyst cannot catalyse a reaction of the poison,
becomes inactive because the active sites are blocked
Regeneration of catalysts in cracking
soot blocks the adsorption of reactant molecules, catalyst is continuously recycled through a separate container where hot air is blown through the powder, the carbon is converted to CO2
Zeolites
catalysts used in the cracking of long chain hydrocarbons