Chemistry (Paper 1) Flashcards
Who developed the periodic table?
Dmitri Mendeleev
Who created the Billiard Ball Model?
Dalton
What model did JJ Thompson propose?
The plum pudding model
Who created the Bohr model?
Rutherford
What type of elements are involved in ionic bonding?
A metal and non metal
Relative mass of an electron
0
What is an ion?
A charged atom
What type of bonding involves only non metals?
Covalent bonding
Ionic bond definition
Electrostatic attraction between oppositely charged ions (when electrons are transferred from metal atoms to non metal atoms)
Electrostatic force
A force of attraction between particles with opposite charges
What is filtration?
Method that separates an insoluble solid from a liquid
Ionic compounds exist as
Giant ionic lattices
Electricity definition
A flow of charge
Why do ionic lattices have high melting and boiling points?
Large amounts of energy is required to break the strong ionic bonds
Why do ionic lattices only conduct electricity when liquid or dissolved in water
The ions are free to move and so charge can flow through the structure.
The number of electrons an atom needs to get a full outer shell in covalent bonding is equal to
the number of bonds that an atom can form
Intermolecular force
A force between molecules
Weak intermolecular forces are overcome when..
simple molecular structures melt or boil
Simple molecular structures have no
overall charge
Covalent bond definition
Shared pair of electrons (between non metals)
Simple molecular structures are usually liquids or gases because
the intermolecular forces are so weak, not much energy is required
small molecules have a low boiling point whilst large molecules have a higher boiling point because..
as the size of the simple molecule increases so does the strength of the intermolecular forces therefore more energy is required to break/overcome the forces
What element is diamond, graphite and fullerene made of?
Carbon
Polymers are
Long chain of molecules held together by strong covalent bonds
Why are polymers solid at room temperature?
The intermolecular forces are relatively strong.
Polyatomic ions definition
• Ions made from more than one charged atom (and are covalently bonded together)
• Eg Nitrate (NO3 -)
Formula for Nitrate
NO3-
Sulfate formula
SO4 2-
Hydroxide formula
OH-
Carbonate formula
CO3 2-
Ammonium formula
NH4 +
Pure metals are (soft/hard)
Soft
Alloys are (soft/hard)
Hard
Why are pure metals soft?
The atoms are the same size therefore they are in an orderly arrangement and layers are able to slide over each other (malleable)
Why are alloys hard?
The atoms are different sizes therefore there is a disorderly arrangement and the layers are distorted. Therefore layers can’t slide over each other
Molecule definition
Atoms chemically bonded together
Why is a diamond very hard?
• It is a giant covalent lattice with 4 strong covalent bonds between each atom
• A large amount of energy is required to break the bonds apart
Allotrope definition
A different structural form of an element eg Diamond and Graphite
What does PANIC stand for?
Positive Anode, Negative Is Cathode
Graphene
• A single layer of graphite
• Used for drug delivery or in electronics
Properties of transition metals (1)
• Less reactive than group 1 metals
• shiny and malleable
• sonorous
• electricity and heat conductor
Properties of transition metals (2)
• catalysts for chemical reactions
• form coloured compounds
• high melting and boiling points
• able to have different charges
Electroplating definition
Using electrolysis to coat an object in a thin layer of a metal
What is electroplating used for?
To protect objects from corroding or to improve its appearance
What is the structure of a metal?
A lattice of positive metal ions attracted to delocalised electrons
Alloy definition
Mixture of a metal with small amounts of other elements
What elements are found in steel?
Iron (main element) and carbon
What elements are found in brass?
Copper (main element) and zinc
What elements are found in bronze?
Copper (main element) and tin
What elements are found in an aluminium alloy (aka magnalium)
Aluminium (main element) and magnesium
Corrosion definition
Destruction of materials by reaction with water and/or oxygen
Rusting definition
Corrosion of iron or steel
Electrolyte definition
an ionic compound that is dissolved in water and conducts electricity during electrolysis
Positive electrode
Anode
Negative electrode
Cathode
Why do solid ionic compounds not conduct electricity?
Their ions aren’t free to move therefore charge is unable to flow through the structure
What is zinc beneficial for?
killing bacteria
How does sacrificial protection work?
When a more reactive metal is used to coat a metal so that it corrodes instead
Empirical formulae meaning
The simplest whole number ratio of atoms or ions in a substance
How are chemical reactions sped up?
By heating them
How to find empirical formula?
• Mass or percentage of the atom/ion over the atomic masses
• Divide results by the smallest answer
• Use the ratio as the subscripts
Concentration equation
Mass/Volume
Negative ion
Anion
Methods for corrosion prevention
Electroplating and sacrificial protection
unit for concentration
g dm-3
Law of conservation of mass
The mass of reactants and products are the same in a reaction
Mole meaning
Unit for measuring the number of particles
Relationship between a mole and Avogadro’s constant
1 mole of a substance contains 6.02 x10^23 particles of that substance
RFM meaning
Relative formula mass (sum of atomic masses of the elements in the molecule)
How can the concentration of a solution be increased?
•Increasing the mass of the solute • decreasing volume of solvent
Concentration definition
How much solute is dissolved in a volume of solvent
Equation to work out the Mass of a substance
Mr x moles
1 dm3 =
1L or 1000cm3
Experiment to find the mass of oxygen reacting with magnesium
• strongly heat magnesium ribbon in crucible • lift lid occasionally to let in oxygen • measure mass of magnesium oxide at end • subtract the mass of magnesium at start
1 ton = how many grams
1,000,000 grams
1 mg = how many grams
1/1000 grams
1 mole of a substance weighs the same as
the Ar or Mr of the substance (in grams)
What are the 4 separation techniques?
filtration, crystallisation, distillation and chromatography
Crystallisation
• To make crystals out of a solution by evaporating it
• Separates a soluble salt from a solution
How to calculate percentage yield
Actual yield / theoretical yield x 100
Toxic meaning
Something that causes death
Why are reagents used in excess?
To ensure all of the other reactant reacts
What does reagent mean?
Reactant
Limiting reagent meaning
A reagent not in excess that limits how much product is made
Yield definition
The mass of product produced by a chemical reaction
Stoichiometry meaning
Ratio of moles that react
Why do some reactions produces a small yield?
• Unwanted side reactions
• Incomplete reactions
• Product left behind on apparatus
What are the diatomic elements?
hydrogen (H), nitrogen (N), oxygen (O), fluorine (F), chlorine (Cl), bromine (Br), and iodine (I)
What is concentration measured in (using moles)?
Mol/dm³
Equation to work out moles (from the concentration of a solution)
Concentration x volume
Unit for measuring volume
dm³
What’s a titration?
An accurate method to measure the concentration of acids and alkalis