Chemistry Exam 5 Flashcards
Another highly specialized type of proteins are the
enzymes
Enzymes function primarily as
organic catalysts
agents which may alter chemical reaction without itself begin permanently changed (used up)
catalysts
naming of enzymes
nomenclature
The compound or type of compound upon which an enzyme works
substrate
most enzymes are named by adding this suffix to the root name of the substrate
ase
catalysts the breakdown of its substrate urea
urease
two general classes of enzymes
proteases
lipases
enzymes which breakdown proteins
proteases
enzymes which breakdown lipids (fats & oils)
lipases
those enzymes catalyzing the decomposition of human remains are generally __________ and __________ in nature
proteolytic
hydrolytic
Splitting or tearing apart of compounds by the addition of water. 2nd definition: a chemical reaction between a salt and water which yields or produces an acid and base of equal strength
hydrolysis
The two distinct sources of putrefactive catalysts
saprophytic bacteria
lysosomes
organisms that obtain their food from dead organic matter
saprophytic bacteria
special structure in certain cells, upon death of a cell releases autolytic enzyme; a chemical defense against infection; present in tears
lysosomes - lysozyme – bactericidal
A unique characteristic of lysosomes (cells) are their ability to self-digest surrounding cellular substances. This self-cell digestion is referred to as
autolysis
carbohydrates are composed of
carbon, hydrogen, and oxygen
carbohydrates are structurally _________ and ______ derivatives of ___________
aldehyde
ketone
polyhydroxy alcohols
three important aspects of carbohydrates
1) Carbohydrates will have at least four (4) or more OH Groups since they are polyhydroxy alcohols.
2) If it was an aldehyde derivative you would find the carbohydrate on an end carbon.
3) If it was ketone derivative you would find the carbohydrate off a non-end carbon.
simple sugars which cannot be hydrolyzed into smaller carbohydrate molecules. They do not undergo hydrolysis
monosaccharides
simple sugars that contain 6 carbons
hexoses
these two simple sugars occur freely in nature
glucose and fructose
common name for glucose
blood sugar
what is the molecular formula for glucose
C6H12O6
simple sugar that is derived from an aldehyde; carbonyl group is attached to an end carbon
aldose
glucose is an (aldose/ketose)
aldose
a sugar derived from a ketone; carbonyl group is attached to non-end carbon
ketose
common name for fructose
fruit sugar
a monosaccharide with 3 carbons
triose
a monosaccharide with 4 carbons
tetrose
a monosaccharide with 5 carbons
pentose
a monosaccharide with 6 carbons
hexose
a monosaccharide with 7 carbons
heptose
are carbohydrates that can be hydrolyzed into two (2) monosaccharides. They are formed when 2 monosaccharides combine by splitting a molecule of water.
disaccharides
three major disaccharides
lactose
maltose
sucrose
a disaccharide: also called milk sugar; the basis for lactic acid in milk
lactose
a disaccharide: also called malt sugar or grain sugar; found in germinating grains
maltose
a disaccharide: also called table sugar, cane sugar, or beet sugar; from sugar canes and beets
sucrose
complex sugars; those carbohydrates which yield many (three or more) monosaccharides upon hydrolysis.
polysaccharides
an example of a polysaccharide: potatoes& crackers
starch
an example of a polysaccharide: stored from of glucose
glycogen
an example of a polysaccharide: substance that termites can break down, but we can’t
cellulose
the breakdown of a compound into simpler units by addition of the components of water
hydrolysis
do not undergo hydrolysis
monosaccharides
upon hydrolysis form two monosaccharides
disaccharides
are first hydrolyzed into two or more dissachrides then complete yield many monosaccharides
polysaccharides
The process by which carbohydrates decompose by enzymes
fermentation
starch in grains may be used as a source of
ethyl alcohol
the bursting of sugar
saccharolysis
the branch of chemistry that deals with compounds produced by living organisms
biochemistry
are biochemical compounds of major importance; defined as - an organic compound containing carbon, hydrogen, oxygen, nitrogen, sulfur and sometimes phosphorus (P) and iron (Fe) and polymers of amino acids
proteins
the decomposition of proteins
proteolysis
compounds which contain two functional groups: the carboxyl group - COOH and the amino group - NH2. These are the building blocks of proteins
amino acids
The simplest amino acid
glycine
glycine is a member of what group
COOH
all amino acids have both the _________ group and the ________ group; therefore, they too may act as acids and bases.
carboxyl
amino
properties of amino acids
amphoteric
buffers
the ability of a substance, such as an amino acid, to act as an acid or base.
amphoretic
any compounds that protects a solution against changes in pH
Buffers
By definition, a protein is a chain of amino acids joined together by the
peptide linkage
Glycine and alanine can be joined to each other by the elimination of one molecule of water to form a
dipeptide
decomposition of proteins either in putrefaction or decay
Proteolysis
The anaerobic decomposition of proteins brought about by the action of enzymes is called
putrefaction
the decomposition of proteins by enzymes of aerobic bacteria
Decay
Putrefaction involves three major chemical reactions:
hydrolysis
deamination
decarboxylation
the final hydrolytic products of putrefaction
amino acids
the absorption of the liquid portion of blood by the surrounding tissue following death
imbibition
the removal of the amino group from the amino acid; formaldehyde reacts with ammonia to produce hexamathylene tetraamine (utrotopin)
deamination
the removal of the carboxyl group from an amino acid to yield carbon dioxide water and an amine
decarboxylation
The final decomposition products are:
1) Hydrocarbons
2) Organic acids
3) Amines (NH2) and ammonia (NH3)- functional group- amino
4) Carbon dioxide
5) Hydrogen sulfide - Sulfur
function as the insulating layer of the body. The structural component in cell membranes and as storage as energy
Lipids
Lipids are commonly referred to as
fats and oils
Properties of lipids:
1) Insoluble in water.
2) Soluble in organic solvents.
3) Have the same elements present as do sugars and carbohydrates (carbon, hydrogen, and oxygen). The insolubility of lipids distinguishes them from carbohydrates.
Lipids are classified on the basis of
their hydrolysis products
are products of hydrolysis which produces fatty acids and glycerol are those products of fats and oils. Compounds whose products of hydrolysis are fatty acids and alcohols
Simple lipids
whether the lipids is a fat or oil depends on
its physical state
a simple lipid; which at room temperature is solid or semi-solid. It contains a high percentage of saturated fatty acids
fat
a simple lipid; which at room temperature is solid or semi-solid. They are liquid and contain a high percentage of unsaturated fatty acids
oil
physical properties of simple lipids
solubility and emusification
- The act of mixing two insoluble liquids
emulsification
the measure of how well two substances mix
solubility
physical state of lipids
fats are solid at room temperature and oils are liquid at room temperature
chemical changes of lipids
final products of hydrolysis
saponification (only associated with fats)
A chemical property of lipids is when fatty acids or oils are boiled (soap making) - a reaction between a fatty acid and strong base which produces glycerol and salt of a fatty acid - (a soap). Although the products are technically salts, commonly they are referred to as soap.
saponification
a white waxy material produced by saponification of body fat. If a body is buried in alkaline soil. It can be produced over a period of time; also known as grave wax
adipocere
lipids formed from combo of unsaturated and/or saturated fatty acids with high molecular weight alcohols, others than glycerol
waxes
Examples of waxes: beeswax, carnuba, lanolin
beeswax, carnuba, lanolin
A common name for any fat/oil
triglyceride
are those products of hydrolysis which result in fatty acids, an alcohol and other compounds
compound lipids
types of compound lipids
a. Glycolipids
b. Sphingolipids
c. Phosolipids
various steroids such as cholesterol hormones
Miscellaneous lipids (Derived lipids)
three types of miscellaneous lipids (derived lipids)
a. Terpenes- menthol, rubber
b. Steroids
c. Cholesterol
high density lipoprotein 200 or less
HDL
good cholesterol
low density lipoprotein 130 or above
LDL
bad cholesterol
very low density lipoprotein
VLDL