Chem Flashcards

1
Q

Bond Polarity

A

-Determined by electronegativity
-measure of how electrons are shared between atoms in a bond

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2
Q

Non polar covalent

A

-Small
-0-0.4
-Shared equally, no charges

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3
Q

Polar covalent

A

-intermediate
-0.4-2.0
-Shared unequally, partial charges

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4
Q

Ionic

A

-Large
-2+
-Complete transfer, full charges

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5
Q

Columbs law

A

-Like charges repel
-Bigger distance decreases attraction
-Bigger the charge, bigger the force (attraction/repulsion)
-Charges more important

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5
Q

Ic vs Ous

A

-Higher charged ions
vs
-Lower charged ions

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6
Q

Periodic table metal trend

A

Left: Metals
Transition line: Metalloids
Right: Non-Metals

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7
Q

Periodic table ionization, affinity, effective nuclear charge trend

A

-increases moving right, decreases moving down

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8
Q

Alaklimetals (first row) reactivity periodic table trend

A

Increases as you move down

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9
Q

Lattice Energy

A

-Higher = higher melting point
-Higher = more negative, stronger
-Smaller ions can get closer together (less protons), stronger
-Negative = good

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10
Q

Ionic vs Covalent bond

A
  • Complete transfer (electrostatic attraction)
    vs
  • Sharing (molecules)
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11
Q

Bond formation graph

A
  • As 2 atoms get closer together PE goes down
    -Optimal bond distance, PE at min, stable
  • Repulsion goes up when atoms overlap too much, E required to break, not stable
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12
Q

Resonance

A

Moving electrons around, not atoms

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13
Q

Electronegativity trend

A

-Increases from bottom left up to top right
-Top right (F) most electronegative
-Noble gases are not

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14
Q

Electronegativity defintion

A

Ability of an atom to attract and hold onto shared electrons in a bond

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15
Q

Electronic vs molecular geometries

A

-Arrangement of all electron pairs, bonding and non bonding (regions of electron density) 5 geometries
vs
-Arrangement of atoms in a molecule

16
Q

Bond angle distortions

A

-Lone pairs: decrease
-Double bonds: Increases touching double bond, decreases not touching double bond (takes more space)

17
Q

double bond angles

A

330 alone- 116 not touching, 122 touching
330 with 2 centrals- 117 not touching

18
Q

Line structure rules

A
  1. Apply octet
  2. Apply formal charges
  3. Geometries
    -N get lone pairs, C get H
19
Q

Oxoacids

A

H bonded to O

20
Q

How to find bond length

A
  • add number of bonds in each domain in ONE structure, then divide by the NUMBER of resonance structures