Chapter 8.1.2 (Exam 2) Energy Flashcards
Chemical Transformations Involve Energy and Energy Transfers
What is entropy (S)?
a measure of the disorder in a system
Why does disorder tend to increase? How does this relate to an organism’s intake of energy?
Disorder tends to increase because of energy transformations
Living organisms must have a constant supply of energy to maintain order
What is enthalpy (H) in biological systems?
Total energy
What is free energy (G) in biological systems?
Usable energy that can do work
How is entropy expressed in biological systems?
Unusable energy is represented by entropy (S) multiplied by the absolute temperature (T)
Change in energy can be measured in calories or joules. What is the formula for change in free energy (ΔG) of a chemical reaction?
ΔG = ΔH - TΔS
ΔG = Gproducts - Greactants
Explain the spontaneity of a chemical reaction.
If ΔG is +, free energy is required, nonspontaneous reaction
If ΔG is –, free energy is released, spontaneous reaction
Describe endergonic reactions.
Endergonic reactions require free energy
Anabolism makes a single product (a highly ordered substance) out of many smaller reactants (less ordered)—complexity (order) increases
Describe exergonic reactions.
Exergonic reactions release free energy
Catabolism breaks down an ordered reactant into smaller, more randomly distributed products—complexity decreases (generates disorder)
Chemical reactions are reversible. What does the direction of the reaction depend on?
The concentration of the reactants and the products
What is chemical equilibrium?
Chemical equilibrium: balance between forward and reverse reactions, a state of no net change, ΔG = 0