Chapter 2.4.3 (Exam 1) Acids and Bases Flashcards
The Properties of Water Are Critical to the Chemistry of Life
What are acids?
Acids release hydrogen ions (H+) in water
H+ concentration is increased; the solution is acidic
What is the effect of too many H+ ions in a solution?
H+ ions can attach to other molecules and change their properties
Biological compounds containing a __________ group are acids.
carboxyl
What is the difference between weak acids and strong acids?
Weak acids: Not all the acid molecules dissociate into ions (e.g., acetic acid CH3COOH)
Strong acids, such as hydrochloric acid (HCl), dissociate completely
What are bases?
Bases accept H+ ions
What is the difference between weak bases and strong bases?
Weak bases: Not all the base molecules dissociate into ions (e.g., HCO3-)
Strong bases, such as sodium hydroxide (NaOH), dissociate completely
How does water act as both a weak acid and a weak base?
Water has a slight tendency to ionize:
H2O <–> H+ + OH-
The hydroxide anion can accept hydrogen, and the hydrogen cation can be donated
Why is water’s tendency to ionize important?
Ionization of water is important because of the abundance of water in living systems and the reactive nature of the H+ ions
What is pH?
negative log of the molar concentration of free H+ ions in the solution:
pH = –log[H+]
In other words, it’s the measure of hydrogen ion concentration within a solution
What is the H+ concentration of pure water?
10-7, or pH = 7
How do pH numbers relate with acidity and H+ concentration?
Lower pH numbers mean higher H+ concentration and greater acidity.
Higher pH numbers mean lower H+ concentration and greater alkalinity.
Why is pH biologically important?
pH influences rates of biological reactions and can change the 3-D structure of biological molecules, which impacts function
Organisms use many mechanisms to minimize change in pH in their cells and tissues
What is one way living organisms are able to maintain a constant internal pH for homeostasis?
Buffers help maintain constant pH
What is a buffer?
a weak acid and its corresponding base, e.g.,
carbonic acid (H2CO3), and
bicarbonate ion (HCO3-)
HCO3- + H+ <–> H2CO3