Chapter 7 Flashcards
cyclized carbs can be found in two forms
- six membered sugar ring - pyranose
- five membered ring - furanose
cyclization of glucose creates
tow asymetric stereoisomers alpha and beta
glucose cyclization - alpha and beta
alpha - if hydroxyl of carbon is below the plane of the sugar
beta - if the hydroxyl of carbon is above the plane of the sugar
the end of a chain with a free anomeric carbin is
reducing end of the polymer
homopolysaccharides and herteropylsaccharides
- polymers contains a single type of monosaccharide
- polymers contains more than one type of monosaccharide
D glucose is stored and examples
intracellularly in both plants (starch) and animals (glycogen)
amylose
linear polymer of glucose residues alpha (1-4) bonds
amylopectin
has alpha(1-4) linked glucose residues with alpha(1-6) every 24-30 residues
structure of glycogen
-structurally identical to amylopectin with higher frequency (every 10 residues)
greater frequency of branch points allows
for rapid mobilization