Chapter 4 Flashcards
The materials physical and chemical properties affect how it behaves, determine the harm it can cause, and influence the effect it may have on all it contacts.
physical, chemical
First responders need to know how to collect hazard and response data that provide information about the substance’s physical and chemical properties.
hazard, response data
At a hazmat incident, try to identify the materials physical state as early as possible.
physical state
The material’s state of matter will indicate how mobile that material may become and can help determine if there will be far reaching hazardous properties.
state of matter
Awareness of hazardous material mobility helps rescuers determine control zones and evacuation distances.
material mobility
Compressible substance, with no specific volume, that tends to assume the shape of a container.
Gas
Incompressible substance with constant volume that assumes the shape of its container.
Liquid
Substance that has a definite shape and size.
Solid
Gases, liquids, and solids behave very differently. Knowing the state of matter will provide clues on how the incident may progress.
state of matter
Understanding a material’s behavior enables responders to identify potential hazards as well as protective actions that should be taken.
behavior
In general, solids are the least mobile and gases have the greatest mobility.
gases
Solid particle that is formed or generated from solid organic or inorganic materials by reducing its size through mechanical process.
dust
Suspension of particles that form when material from a volatilized solid condenses in cool air.
fume
Finely divided liquid suspended in the atmosphere.
Mist
Form of pressurized mist characterized by highly respirable, minute liquid or solid particles.
aerosol
Solid particle whose length is several times greater than its diameter is formed by a disruption of the natural state.
Fiber
Gaseous form of a material that is normally in a solid or liquid state at room temp and pressure.
vapor
Visible aerosol of a liquid formed by condensation.
fog
Gases have an undefined shape and volume and keep expanding if uncontained
undefined shape
Research has shown that 1 and 2 ton quantities of chlorine and anhydrous ammonia released in an open area both initially spread in a 360 radius before being dispersed downwind in some situations.
360
Gases may travel in unexpected ways, depending on many factors including air movement, topography, and barriers such as walls or buildings.
topography
The conversion of a liquid to a vapor increases both the hazardous materials mobility and the challenges responders face when dealing with the material.
liquid, vapor
Micron is the unit of measure typically used to express particle size.
Micron
Physical properties are the characteristics of a material that do not involve the chemistry or chemical nature of the material.
Physical properties
Vapor pressure is the pressure exerted by a saturated vapor above its own liquid in a closed container.
Vapor pressure
A liquids vapor pressure increases as the temp rises.
rises
The lower the boiling point of a material, the higher its vapor pressure will be.
vapor pressure
If you know the vapor pressure of a material, you can use it as a general gauge to tell how fast a product will evaporate under normal circumstances.
evaporate
Boiling point is the temp at which a liquid changes to a gas at a given pressure.
Boiling point
Flammable materials with low boiling points generally present special fire hazards.
low boiling points
melting point is the temp at which a solid substance changes to a liquid state at normal atmospheric pressure.
melting point
Some substances will actually sublimate or change directly from a solid into a gas without going into a liquid state in between.
sublimate
Vapor density is the weight of a given volume of pure vapor or gas compared to the weight of an equal volume of dry air at the same temperature and pressure.
Vapor density
Solubility in water expresses the percentage of a material that will dissolve in water at ambient temp.
Solubility
A material in which the positive and negative charges are permanently separated, resulting in their ability to ionize in solution and create electrical conductivity.
Polar solvent
Irritant agents that are water soluble usually cause early upper respiratory tract irritation, resulting in coughing and throat irritation.
water soluble
Partially water soluble chemicals will penetrate into the lower respiratory system and cause delayed symptoms that include breathing difficulties, pulmonary edema, and coughing up blood.
Partially water soluble
Materials with higher degrees of solubility are easier to control with water.
solubility
Miscibility describes the ability of two or more gases or liquids to mix with or dissolve into each other.
Miscibility
Incapable of being mixed or blended with another substance.
Immiscible
Specific gravity is the ratio of the density of a material to the density of a standard material, usually an equal volume of water, standard conditions of pressure and temp.
Specific gravity
Solubility plays an important role in specific gravity.
Solubility
The persistence of a chemical is its ability to remain in the environment.
persistence
Persistent nerve agents will remain effective at their point of dispersion for a much longer time than nonpersistent nerve agents.
dispersion
Viscosity is the measure of the thickness or flowability of a liquid at a given temp.
Viscosity
Odor threshold is the concentration at which the average person can smell a particular compound.
Odor threshold
Chemical properties describe the chemical nature of a material and the behaviors and interactions that occur at a molecular level.
Chemical properties
Flash point is the minimum temp at which a liquid or volatile solid gives off sufficient vapors at its lower explosive limit.
Flash point
Fire point is the temp at which a liquid or volatile substance gives off enough vapors to support continuous burning.
Fire point
Liquids that have low flash points and burn easily are designated as flammable liquids, whereas liquids with higher flash points that do not burn as easily are called combustible liquids.
flammable liquids, combustible liquids
The autoignition temperature of a substance is the minimum temp to which the fuel in air must be heated to initiate self sustained combustion without initiation from an independent ignition source.
autoignition temperature
Any liquid having a flash point below 100*F and a vapor pressure not exceeding 40 psi
flammable liquid
Liquid having a flash point at or above 100F and below 200F.
combustible liquid
The lowest temp at which a combustible material ignites in air without a spark or flame.
Autoignition temp
Minimum temp to which a fuel in air must be heated in order to start self sustained combustion independent of the heating source.
ignition temperature
The corrosivity of acids and bases is often measured or expressed in terms of pH.
pH
Any chemical that ionizes to yield hydrogen ions in water.
Acid
A water soluble compound that chemically dissociates in water to form a negatively charged hydroxide ion.
Base
Bases react with an acid to form a salt by releasing an unshared pair of electrons to the acid or by receiving a proton.
electrons
Bases often cause more eye damage than acids due to the longer duration of exposure.
eye damage
A common sign of exposure to a base is a greasy or slick feeling of the skin, which is caused by saponification the breakdown of fatty tissues.
saponification
Compound containing hydrogen that reacts with water to produce hydrogen ions; a proton donor, a liquid compound with a pH less than 7.
Acid
Atom that has lost or gained an electron, giving it a positive or negative charge.
Ion
Any alkaline or caustic substance, corrosive water soluble compound or substance containing group forming hydroxide ions in water solution that reacts with an acid to form a salt.
Base
Process of splitting a molecule or iconic compounds into smaller particles, especially if the process is reversible.
Dissociation
Reaction between an alkaline and a fatty acid that produces soap.
Saponification
Solution that has a pH between 7 and 14.
Basic solution
Ability of a substance to chemically react with other materials, and the speed with which that reaction takes place.
Reactivity
Substance capable of chemically reacting with other substances, for example, material that reacts violently when combined with air or water.
Reactive material
The chemical reactivity of a substance describes its relative ability to undergo a chemical reaction with itself or other materials.
relative ability
Minimum energy that starts a chemical reaction when added to an atomic or molecular system.
Activation energy
Many reactions need an oxidizing agent, a reducing agent, and some kind of activation energy to get them started.
oxidizing agent
Activation energy is the energy needed to start the reaction, much like a blasting cap activating dynamite.
dynamite
First responders may see terms as light sensitive, heat sensitive, or shock sensitive on SDSs and/or manufacturers/labels, indicating that those products have an increased susceptibility to those sources of activation energy.
activation energy
Stability and reactivity are important factors in chemical interactions.
Stability, reactivity
An asphalt roadway could explode if liquid oxygen spills on it and is accompanied by sufficient activation energy.
liquid oxygen
Oxidation reduction reactions can be extremely violent and dangerous because they release a tremendous amount of energy.
Oxidation reduction reactions
Polymerization is a chemical reaction in which simple molecules combine to form long chain molecules.
Polymerization
catalysts will increase the rate of polymerization and decrease the activation energy necessary for further polymerization.
catalysts
Materials that may undergo violent polymerization if subjected to heat or contamination are designated with a P in the blue and yellow sections of the ERG.
P
Inhibitors are materials that are added to products that easily polymerize in order to control or prevent an undesired reaction.
Inhibitors
Liquid oxygen is a powerful oxidizer. If spilled on asphalt, very little activation energy is needed to cause an explosion.
oxidizer
Fuel that is being oxidized or burned during combustion.
Reducing agent
Substance that readily gives off large quantities of oxygen.
Strong oxidizer
Time sensitive inhibitors are added to Liquid styrene before it is shipped.
Liquid styrene
The least energetic form of radiation is nonionizing radiation such as visible light and radio waves.
nonionizing radiation
The most energetic form of radiation is ionizing radiation.
ionizing radiation
Series of energy waves composed of oscillating electric and magnetic fields traveling at the speed of light.
nonionizing radiation
Radiation that causes a chemical change in atoms by removing their electrons.
ionizing radiation
Ionizing radiation can be divided into four types: alpha, beta, gamma, and neutron
alpha, beta, gamma, and neutron
Energetic, positively charged alpha particles emitted from the nucleus during radioactive decay that rapidly lose energy when passing through matter. Alpha- blocked by dead layer of skin
Alpha- blocked by dead layer of skin
Alpha particles lose energy rapidly when traveling through matter and do not penetrate deeply. Can be stopped by a sheet of paper
Alpha particles- can be stopped by a sheet of paper
During radioactive decay , alpha particles are emitted from the nucleus of an atom, forming a new element
radioactive decay
Neutron radiation is the hardest to protect against because it is highly penetrating.
Neutron radiation