Carbohydrates Prt. 2 - Oligosaccharides And Polysaccharides Flashcards

1
Q

any of the carbohydrates that contain 2-10 monosaccharide unit

A

OLIGOSACCHARIDES

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2
Q

Contain 2 monosaccharides units joined by a glycosidic bone

A

DISACCHARIDES

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3
Q

DISACCHARIDES (4)

A

Maltose
Lactose
Sucrose
Isomaltose

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4
Q

Disaccharides are formed by_________ reactions between two monosaccharides

A

condensation

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5
Q

Glucose + Galactose

A

Lactose

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6
Q

Synthesized by mammary gland during lactation

A

Lacoste

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7
Q

is a medium for penicillin production

A

Lactose

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8
Q
  • important antibiotic with coverage for gram positive
A

Penicillin

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9
Q

is a diluent for different drugs

A

Milk

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10
Q

Glucose + Fructose

A

Sucrose

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11
Q

Table sugar;
most prevalent

A

Sucrose

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12
Q

Non-reducing sugar; no hemiacetal present and exist only as one form

A

Sucrose

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13
Q

• MOST ABUNDANT SUGAR present in all plants
• The sweetening agent known as cane sugar

A

Sucrose

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14
Q

Glucose + Glucose

A

Maltose

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15
Q

Important in Brewing beer

A

Maltose

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16
Q

Consists of 2 units of D-glucose

A

Maltose

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17
Q
  • Juice from barley
A

Malt

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18
Q

• Produced whenever polysaccharides starch also breaks down

• Common ingredient for baby food»

A

Maltose

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19
Q

Any sugar’ containing a hemiacetal is a

A

reducing sugar

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20
Q

• one OH group and one O-R group attached to same carbon

• in equilibrium with aldehyde/ketone

A

Hemiacetal

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21
Q

• two O-R groups attached to same carbon

• not in equilibrium with aldehyde/ketone (“locked”)

A

Acetal (Ketal)

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22
Q

Sugars with a________ are in equilibrium with a ring-opened form containing an aldehyde and will react as a reducing agent toward certain (oxidizing) metal salts

A

hemiacetal

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23
Q

A sugar without a hemiacetal is a non-

A

reducing sugar

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24
Q

are “locked” and not in equilibrium with a ring-opened form with an aldehyde.

They will therefore not react as a reducing agent.

A

Acetals

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25
REDUCING SUGAR _____ monosaccharides ______ disaccharides (maltose & lactose)
ALL SOME
26
A _________ gives a brick-red precipitate on heating with Benedict's solution.
reducing sugar
27
Maltose and lactose are ______ sugar
reducing sugars
28
Sucrose is a_________ sugar
non reducing sugar
29
carbohydrate containing a large number of monosaccharide units, each joined to the next by one or more glycosidic bonds
POLYSACCHARIDES
30
POLYSACCHARIDES aka
GLYCAN
31
Negative in Benedict's test (and Tollens)
Polysaccharides
32
Also have limited water solubility because of their size (has a jelly-like consistency when placed in water)
Polysaccharides
33
FUNCTIONS of polysaccharides
1) Food & energy 2) Structural materials
34
2 TYPES OF POLYSACCHARIDES
1. HOMOPOLYSACCHARIDES 2. HETEROPOLYSACCHARIDES
35
• Contain only a single type of monosaccharides
HOMOPOLYSACCHARIDES
36
• Complex carbohydrates formed by combining carbohydrates with noncarbohydrates or carbohydrate derivatives
HETEROPOLYSACCHARIDES
37
Examples of polysaccharides:
Starch Glycogen Cellulose
38
consists of: • Long chains of -glucose residues - (about 10, 000) per chain
Cellulose
39
unbranched glucose polymer Most abundant naturally occurring polysaccharides
Cellulose
40
• Structural component of cell walls in plants • is fibrous, tasteless, odorless and insoluble in water and most organic solvents
Cellulose
41
• is a linear polysaccharide of D-glucose units joined by beta-1,4-glycosidic bonds • Has a beta configuration, unlike amylose which has an alpha configuration
Cellulose
42
______ is: • A polymer of a-glucose
Starch
43
used for energy storage in plants complete hydrolysis yields only D-Glucose
Starch
44
Starch is a_____________type because it contains only glucose monosaccharides
homopolysaccharide
45
Two types of starch grains:
Amylose Amylopectin
46
• Being linear, is less readily digested • Being linear, it takes up less space
Amylose
47
• Easy to breakdown by enzymes to release glucose when needed
Amylopectin
48
is often used to test for the presence of starch in any solution. If starch is present in the solution, if iodine is added, it will turn into dark blue-black color (positive results of starch)
lodine
49
• Also known as animal starch • Acts as an energy reserve for animals
GLYCOGEN
50
Branched type of polysaccharide containing 106 glucose units Joined together by glycosidic bonds called alpha-1,4 and alpha-1,6 Is a polymer of a-glucose
GLYCOGEN
51
Similar to amylopectin, but side branches: Occur more frequently Are more branched
Glycogen
52
serves as a buffer to maintain glucose level in body
Glycogen
53
Chemically modified polysaccharides • Some carbohydrates are chemically modified by the addition of functional groups, such as:
Phosphate Amino groups
54
• widely used injectable blood thinner • usually stored within the secretory granules of mast cells and released only into the vasculature at sites of tissue injury
HEPARIN
55
Chemically modified polysaccharides
PECTIN HEPARIN
56
is a naturally occurring substance (a polysaccharide) found in berries, apples and other fruit When heated together with sugar, it causes a thickening that is characteristic of jams and jellies.
PECTIN
57
is a major component of the middle lamella, where it helps to bind cells together, but is also found in primary cell walls
Pectin
58
second most abundant gives rigidity to the exoskeletons of crabs, lobsters, shrimp, insects, and other arthropods
Chitin
59
found in the cell walls of fungi
Chitin
60
is used commercially in coatings (extends the shelf life of fruits and meats)
Chitin
61
contains alternating residues of N-acetyl-Beta-D-Glucosamine and D-Glucoronate a major component of skin, where it is involved in tissue repair (present in connective tissue layer)
HYALURONIC ACID
62
is a major component of the synovial fluid, and was found to increase the viscosity of the fluid Serves as a lubricant in fluid of our joints Associated with vitreous humor
HYALURONIC ACID
63
Hyaluronic acid came from the Greek word "______" which means glass because it has a glass/clear-like appearance
hyalos
64
The bond that links the two monosaccharides of a disaccharide together is called a
glycosidic linkage
65
In disaccharide formation, one of the monosaccharide reactants functions as a________, and the other functions as an_________.
hemiacetal alcohol