Aldehydes and ketones Flashcards

1
Q

common name?

A
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2
Q

common name?

A
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3
Q

common name?

A
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4
Q

common name?

A

formaldehyde

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5
Q
A
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6
Q
A
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7
Q

what is the IUPAC method for naming aldehydes?

A

lose “e”
add “al”

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8
Q
A
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9
Q

what would cyclopentanal look like?

A

does not exist because cyclic aldehydes cannot exist

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10
Q
A
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11
Q

what is the simplest ketone? its name?

A
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12
Q

what is the common naming method for ketones?

A

alkyl + alkyl + “ketone”

(similar to ethers)

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13
Q
A
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14
Q

what is the IUPAC naming method for ketones?

A

lose “e”
add “one”

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15
Q
A
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16
Q
A
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17
Q
A
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18
Q
A

when O is double bonded to a parent chain, it has -oxo- as substituent name

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19
Q
A
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20
Q
A
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21
Q

if a parent chain has 3-12 carbons, what state is it at room temperature typically?

A

liquid

22
Q

if a parent chain has more than 12 carbons, what state is it at room temperature typically?

A

solid

23
Q

why is it that ketones are only ever H-bond acceptors and never donors?

A

they don’t have a hydrogen directly adjacent to the oxygen for it to donate

24
Q

why is it that all H-bond donors can also be acceptors?

A

If they have a hydrogen to give, it means they must have an adjacent oxygen to receive H-bonds.

25
Q

which is acting as the H-bond donor and which is the H-bond acceptor?

A
26
Q

which is acting as the H-bond donor and which is the H-bond acceptor?

A
27
Q
A
28
Q

what is the name of one common oxidizing agent?

A

potassium dichromate

29
Q
A
30
Q
A
31
Q

what is the purpose of Tollen’s test?

A

test for presence of any aldehydes

32
Q

what does Tollen’s test require?

A

tollen’s reagent
strong base

33
Q
A
34
Q

what does Fehling’s test show positive for?

A

aliphatic aldehydes
alpha hydroxy ketones

35
Q

do aromatic aldehydes show positive on Fehling’s test?

A

no, aliphatic aldehydes do

36
Q

what are the agents within Fehling’s test?

A
37
Q
A
38
Q

is this an aromatic aldehyde?

A

yes

39
Q

is this an aromatic aldehyde?

A

no

40
Q

is this an aromatic aldehyde?

A

no

41
Q
A
42
Q
A
43
Q
A
44
Q
A

hemiacetal

45
Q
A

acetal

46
Q
A

hydrate

47
Q

find the acetal/hemiacetal/hydrate

A
48
Q

include the entire reaction, starting at this point to get an acetal

A
49
Q
A
50
Q
A