Absorption and emission spectrum Flashcards

1
Q

What does an atomic emission spectrum look like

A

black background with coloured lines

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2
Q

What does an atomic absorption spectrum look like

A

coloured background with black lines

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3
Q

What is the equation that relates energy to frequency

A

E = hv

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4
Q

Define the terms in the equation E = hv and give units

A

E = energy (Joules)
h = plancks constant
v = frequency (hertz)

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5
Q

What is the equation that relates wavelength to frequency

A

C = λv

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6
Q

Define the terms in the equation C = λv and give units

A

C = speed of light (m/s)
λ = wavelength (m)
v = frequency (hertz)

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7
Q

Which way are electron moving to give lines on an emission spectra

A

from a higher energy level to a lower energy level

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8
Q

Why does each element have a unique emission spectra

A

each element has unique gaps between the energy levels

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9
Q

Why do the lines on an emission/absorption spectrum get closer together

A

as they get closer when frequency increases as the energy levels become closer together

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10
Q

Why are lined fixed on the spectrum

A

as electrons only exist in certain fixed energy levels and drops in levels gives out a specific amount of energy

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11
Q

What happens to electrons in spectroscopy

A

atoms that are given energy get excited and move into higher energy levels, they fall back down to a lower energy level giving out the energy as light (electromagnetic radiation)

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12
Q

Why are the lines in a atomic spectrum in sets

A

each set is a drop to a specific level

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13
Q

Electromagnetic spectrum

A

radio waves, infrared, visible light, ultraviolet, X-rays, gamma rays

radio -> gamma = decreasing wavelength, increasing frequency and energy

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14
Q

Explain the origin of the lines in an atomic emission spectrum

A

electrons in atoms can only be a certain fixed energy levels, atoms are given energy and electrons are promoted to a higher energy level, they fall back down to lower levels giving out the energy as electromagnetic radiation of frequencies given by (change in) E=hv, there are lots of different possible jumps each giving light of a different frequency and a different line on the spectrum

Diagram

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15
Q

Colour of lithium (flame test)

A

bright red

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16
Q

Colour of sodium (flame test)

A

yellow

17
Q

Colour of potassium (flame test)

A

lilac

18
Q

Colour of calcium (flame test)

A

brick red/orange

19
Q

Colour of copper (flame test)

A

blue green