7.1 Organic Chemistry: Nomenclature Flashcards
How do we systematically name organic chemical compounds?
hydrocarbon prefix nomenclature
(example: alkanes 1-8)
- methane
- ethane
- propane
- butane
- pentane
- hexane
- heptane
- octane
how to name alkanes and alkenes
- count longest connected chain in compound e.g. pentane
- add alkyl groups e.g. two methyl, to make dimethylpentane
- assign numbers left to right and find the alkyl locant with a hyphen, each locant separated by commas, e.g. 2,3-dimethylpentane
- if there are different alkanes/alkenes, add using alphabetical order
draw 3-ethyl-2-methylpentane
..
single carbon bond compound
~ane
double carbon bond compound
~ene
triple carbon bond compound
~yne
drawing expanded formula
every element on branches
drawing condensed formula
every simple compound on branches
drawing skeletal structure
all connected by the bond lines, no labels
hydrocarbon families are a
homologous series
alkanes are
saturated hydrocarbons
C(n) H(2n+2)
saturated hydrocarbons are compounds that…
contains only C and H and single C-C bonds
straight (unbranched) chained alkanes
made up of Cs surrounded by Hs
branched chain alkanes
chained alkanes but with one or more branches
cycloalkanes (ring molecules)
carbons in a circle with H stemming out
alkenes are
unsaturated hydrocarbons
C(n) H(2n)
unsaturated hydrocarbons are compounds that…
contain C and H and double C=C bond
alkynes are
unsaturated hydrocarbons
C(n) H(2n-2)
can react to incorporate more atoms
double or triple bonds are functional groups. draw:
pent-1-ene
pent-2-ene
3-methyl-2-pentyne
structural isomers have…
same molecular formula
different structural formula
chain isomers are…
rearrangement of the chain with more than one alkyl group (hydrocarbon branch)
3 types of isomerism
- chain (moving branches)
- position (moving functional group)
- functional (different functional groups, like from alkene to alkane)
distinguishing characteristic of homologous series:
can be represented by one general molecular formula