1.2: Carbohydrates Flashcards
list the elements that carbohydrates are made from
carbon, hydrogen and oxygen
how many monosaccharides make up a monosaccharide and give an example
1 - glucose
how many monosaccharides make up a disaccharide and give an example
2 - sucrose, maltose, lactose
how many monosaccharides make up a polysaccharide and give an example
many - starch, cellulose, glycogen
what is the general formula for monosaccharides
CnH2nOn
What is the name for a monosaccharide with 3 carbons
triose
What is the name for a monosaccharide with 5 carbons and give 2 examples
pentose - deoxyribose, ribose
What is the name for a monosaccharide with 6 carbons and give 3 examples
hexose - glucose (alpha /beta),fructose, galactose
give 3 examples of disaccharides
maltose, lactose, sucrose
what two monosaccharides make up maltose
glucose and glucose
what two monosaccharides make up lactose
glucose and galactose
what two monosaccharides make up sucrose
glucose and fructose
Monosaccharides are all sugars, list 3 properties of these sugars
sweet, soluble, crystalline
what is a monomer
a single unit that joins together with other monomers to form a polymer e.g. amino acid
what is a polymer
a chain of repeating units (monomers) e.g. protein is made from amino acids
Describe what a condensation reaction is
when one monomer joins to another and a water molecule is removed
Describe what a hydrolysis reaction
when water molecules are added in the process of breaking bonds between molecules
Name two polymers that are formed from alpha glucose monomers and what type of polysaccharide are they?
starch and glycogen
- glucose store
name one polymer that is formed from beta glucose monomers and what type of polysaccharide is it?
cellulose
- structural polymer
what is the difference in structure of alpha and beta glucose
hydroxyl group is below carbon 1 for alpha glucose whereas for beta glucose, it is above carbon 1
Describe the structure of fructose compared to alpha glucose
6 carbons but carbon 2 (with its hydrogen and hydroxyl group) is branched off of carbon 1 making a pentagon shape
describe the structure of galactose compared to alpha glucose
hydroxyl group is above carbon 4 instead of below
What are structural isomers
compounds with the same chemical formula but different structure
list the 3 structural isomers of alpha glucose and explain why
beta glucose, fructose, galactose
because they all have the same number of carbons, oxygens and hydrogens, but have different structures
what is made when reacting two alpha glucose molecules
maltose and water
what is made when reacting beta glucose and galactose together
lactose and water
what is made when reacting alpha glucose and fructose together
sucrose and water
name the covalent bond that is formed between adjacent monomers in a disaccharide/polysaccharide
glycosidic bond
what type of reaction occurs during the formation of a glycosidic bond
condensation reaction
How can you break a glycosidic bond to release monomers
hydrolysis reaction - add water
describe the process by which sucrose can be absorbed into the gut
1 - sucrose is hydrolysed by sucrase into glucose and fructose
2 - glucose and fructose are soluble and can be absorbed through the wall of the ileum
describe the structure and bonding in starch
Polymer of alpha glucose. 30% Amylose: 1-4 bonds, all bonds face downward, helical shape due to strain
70% Amylopectin: 1-4 AND 1-6 bonds, branched
Describe how the structure of starch relates to its function (4 points)
1 - compact shape - takes up little space inside cell
2 - insoluble - osmotically inert
3 - increased surface area (branched) for hydrolysis to release glucose and so faster release of glucose
4 - easily hydrolysed by amylase to provide glucose for respiration
Describe the structure and bonding of cellulose
polymer of beta glucose. Every alternate beta glucose molecule is rotated 180 degrees on horizontal axis. 1-4 glycosidic bonds alternate up/down. Resulting in a straight chain. Multiple cellulose chains form a microfibril. H-bonds form cross links between chains
Describe how the structure of cellulose relates to its function (2 points)
1 - high tensile strength and rigidity due to H bonds between beta glucose polymers
2 - This forms microfibrils suitable for component of plant cell walls for storage
Describe the structure and bonding of glycogen
Similar structure to amylopectin - 1-4 and 1-6 bonds, branched - but more 1-6 bonds and so more branched.
Describe how the structure of glycogen relates to its function (3 points)
1 - very compact shape, so a lot of glucose can be condensed for storage inside cell
2 - insoluble and so osmotically inert
3 - Easily hydrolysed by glycogen phosphorylase to provide glucose for respiration
explain how glycogen in animals means animals have a higher metabolic rate than plants
glycogen in animals is more branched than starch in plants and so a higher surface area for hydrolysis and so more glucose released for respiration