test 11 Flashcards

1
Q

name the 3 types of intermolecular forces

A
  1. dipole-dipole force
  2. hydrogen bonds
  3. dispersion forces
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2
Q

an intermolecular force; the attraction of the positive end of one polar molecule to the negative end of another polar molecule

A

dipole-dipole force

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3
Q

a special dipole-dipole force involving hydrogen and a highly electronegative element

A

hydrogen bonds

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4
Q

when bonded with hydrogen which highly electronegative elements cause the shared electrons to shift away from the hydrogen atoms, because of their greater electronegativity?

A

fluorine, oxygen, or nitrogen.

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5
Q

which intermolecular force is the strongest and why?

A

hydrogen bonds. the combination of a high polarity and proximity produces the strongest

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6
Q

a substance is typically about________ denser as a solid than as a liquid and what is the exception?

A

10% and water

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7
Q

completely describe what happens as water’s temperature drops.

A

down to a temperature of 4*C, water becomes increasingly dense, but as it cools below this temperature, hydrogen bonds and dipole-dipole forces cause water molecules to spread apart from each other, assembling into an open hexagonal lattice. increased space between the molecules causes ice to be less dense than water, which makes it float

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8
Q

ionic and metallic solids are usually___________

A

crystalline

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9
Q

give 5 examples of amorphous solids

A
  1. rubber
  2. some plastics
  3. asphalt
  4. paraffin
  5. amorphous sulfur
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10
Q

the temperature at which a substance changes between the solid and liquid states is called what?

A

melting point

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11
Q

what is the transformation from a solid to a liquid?

A

melting

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12
Q

crystalline substance have _________melting points

A

distinct

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13
Q

the direct change in state from the solid to the gaseous state

A

sublimation

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14
Q

what are the 7 basic crystals

A
  1. cubic
  2. tetreagonal
  3. rhombohedral
  4. triclinic
  5. monoclinic
  6. hexagonal
  7. orthorhombic
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15
Q

elements or compounds that can form more than one type of crystal lattice are called what

A

polymorphous

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16
Q

the ———– of a crystal is the energy released when gaseous particles form crystals

A

lattice energy

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17
Q

the magnitude of the electrical charges in a crystal affects its ——

A

stability

18
Q

why does particle size affect binding forces

A

small particles can be more tightly bound than large particles

19
Q

the ———– of a crystal also affects the binding forces

A

geometric structure

20
Q

what affects the strength of a crystal

A

size of particles
geometric structure
the charges of the particles

21
Q

a substance that is added to a liquid that acts to reduce the surface tension of that liquid by interfering with hydrogen bonds

A

surfactants

22
Q

a liquid’s ability to resist flowing

A

viscosity

23
Q

the reverse of vaporization- it is the formation of a liquid from its gaseous state

A

condensation

24
Q

evaporation is a ——— process

A

cooling

25
Q

what type of attractions allow quick evaporation

A

weak

26
Q

when the two processes of condensation and evaporation balance each other so that no net effect can be observed

A

dynamic equilibrium

27
Q

the temperature at which the vapor pressure equals the applied pressure

A

boiling point

28
Q

what can condense and even solidify any gas

A

low temperatures and high pressures

29
Q

the highest temperature at which a gas can be liquified

A

critical temperature (Tc)

30
Q

when would most evaporation occur

A

high temps

31
Q

what affects evaporation

A

temperature and molecular attraction

32
Q

a solid in which the particles occur in random positions with no orderly pattern. Examples include asphalt and paraffin

A

amorphous solid

33
Q

a state of matter in which the particles have relatively little energy, cannot overcome the attractive forces, and remain in fixed positions with set distances between them. It has fixed a volume and is relatively incompressible

A

solid

34
Q

the basic building block for any type of crystal; the section of a crystal lattice that contains one formula unit of the compound or one repeating segment of the overall lattice strucure

A

unit cell

35
Q

one of two or more forms of a polymorphous element that exists in the same physical state

A

allotropes

36
Q

the curved upper surface of a column of liquid that results from intermolecular attractions within the liquid and between the liquid and its container

A

meniscus

37
Q

the movement of a liquid up a narrow tube caused by adhesion between molecules in the walls of the tube and the molecules of the liquid

A

capillary action

38
Q

a general term for a physical change from the liquid state to the vapor or gaseous state

A

vaporization

39
Q

a physical change from the liquid state to the gaseous state that occurs at the surface of a liquid when the temperature is between the substance’s freezing and boiling points

A

evaporation

40
Q

when pressure is exerted by a vapor in equilibrium its solid or liquid state at a specified temperature

A

vapor pressure

41
Q

a technique used to separate a mixture by evaporating its components at their boiling points and then condensing and collecting the vapors

A

distillation

42
Q

3 types of vaporization

A

evaporation
boiling
condensation