T2.3 Carbohydrates and Lipids Flashcards
Monosaccharide
Single carbohydrate unit
Examples of monosaccharide
Glucose, ribose, fructose, galactose
Disaccharide
2 monosaccharides linked together
Examples of disaccarides
Maltose, sucrose, lactose
Polysaccharide
Multiple monosaccharides linked together
Examples of polysaccharides
Startch cellulose, glycogen, chitin
Condensation reaction
also called dehydration synthesis
Loss of a -OH (hydroxl group) from one molecule and a -H (hydrogen) from another (h2o loss)
Anabolic (builds molecules)
require ATP
Bond created from condensation reactions
Glycosidic bond
The link of one monosaccharide to another occurs between which -OH molecules?
The ones attached to carbon 1 and carbon 4
What is the purpose of the -OH group on carbon 6?
Used to form side branches in amylopectin and glycogen
Difference between alpha and beta glucose
The -OH group on carbon 1 points downward in alpha glucose, while it points up in beta glucose
Cellulose
- Glycosidic linkage of beta glucose
- any glucose that is added to chain has to be position 180% to previous one
- Flat chain
- we cannot digest
- 1-4 linkage
Starch
- linking alpha glucose molecules
- energy storage in plants
- helical chains
Amylose
Form of Starch
1- 4 linkage only
Amylopectin
Form of starch
1-4 and 1-6 linkages
has side branches
Why does cellulose use beta glucose?
The CH2OH on top of the glucose molecule can pack more tightly thank alpha glucose because the molecules alternate sides on which it is on (because of the need for flipping molecules).
It allows more strenth
Glycogen
- Simular to branched startch (Amylopectin) but with more branchings
- Makes molecule more compact and easier to store
- Energy storage in animals
- 1-6 and 1-4 glycosidic linkage of alpha glucose
Ester bond
When an acid (fatty acid) reacts with the -OH group in an alcohol (glycerol), removing water molecules. Used in the creation of triglycerides.
How are triglycerides formed?
Condensation from three fatty acids and one glycerol
Difference between fats and oils
fats - solid at room temp (25 C), liquid at body temp (37 C)
oils - liquid at room temp
Functions of lipids
- long term energy storage
- insulation
- shock absorber for organ
- membrane composition
Cis unsaturated fat description
- Hydrogens are on same side of double bond
- Bend in hydrocarbon chain at double bond
- Poor packing, lowers melting point
- Liquid (oils)
- natural occurance
Trans unsaturated fat description
- Does not have bend in hydrocarbon
- Hydrogens are on opposite sides of double bond
- Strong packing, higher melting point
- solid at room temp
- Artifically produced
Reasons for lipids as long-term storage
Amount of energy released is double the amount of carbohydrates
Why are carbohydrates not used for long term energy storage
Carbohydrates are heavier
1 gram carbohydrate is associated with 2 grams water
fats form pure droplets not associated with water
Saturated fats
No double bonds
Monounsaturated
1 double bond
Polyunsaturated
more than 1 double bond
Example of saturated fat
palmitic acid
Example of monounsaturated fat
palmitoleic acid
Example of polyunsaturated fat
Linolenic acid