resins Flashcards

1
Q

The term is applied to more or less solid, amorphous products of complex chemical nature.

A

RESIN

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2
Q

They are usually formed in schizogenous ducts or cavities and are end product of metabolism.

A

RESIN

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3
Q

Physical property of resin

A

hard, transparent or translucent and upon heating it soften and finally melt

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4
Q

When Heated: Chemically, are complex mixtures of:

A

RESIN ACIDS
RESIN ALCOHOLS (Resinol)
RESIN PHENOLS (Resinotannols)
ESTERS
RESENES

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5
Q

It is a chemically inert compound

A

RESENES

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6
Q

Resins are insoluble in __

A

WATER

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7
Q

Resins are usually insoluble in ___

A

PETROLEUM SPIRITS

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8
Q

Resins are soluble in ___

A

ALCOHOL
CHLOROFORM
ETHERS

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9
Q

Some investigators believe, it is an oxidation products of ___.

A

TERPENES

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10
Q

Several Resins: used in Pharmacy and in Art:

A

GUAIAC
ROSIN
MASTIC

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11
Q

When separated and purified, they are
usually ____ that fuse readily when heated, after passing through a preliminary stage of softening.

A

BRITTLE, AMORPHOUS SOLID

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12
Q

On evaporation, these solutions deposit the resin as a ___

A

VARNISH-LIKE FILM

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13
Q

❑ Burn with characteristic, smoky flame.

A

RESINS

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14
Q

Resins Combinations

A

VOLATILE OILS
GUMS
OIL AND GUMS
BALSAMS
GLYCOSIDAL COMBINATION

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15
Q

Volatile Oils examples

A

OLEORESINS
• Copaiba, Mastic, Capsicum, Ginger,
Turpentine

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16
Q

Gums examples

A

Gum-Resins
• Gamboge

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17
Q

Oil and Gums examples

A

Oleo-gum resins
• Myrrh, Asafoetida, Olibanum

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18
Q

They are water-soluble carbohydrate derivatives; they can be separated from oleoresins rather easily.

A

GUMS

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19
Q

Are resinous mixtures that contain cinnamic acid, benzoic acid or both, or esters of these acids: (Typical Balsams)

20
Q

Examples of Balsam

A

• Balsam of Peru, Balsam of Tolu, Storax

21
Q

This term has been erroneously applied to some oleoresins (balsam of copaiba). This error has been occasionally led to some confusion.

22
Q

Examples of Glycosidal Combination

A

Glucoresins/Glycoresins
• Ipomea, Jalap, Phodophyllum

23
Q

❑ Differ from a resin or resin combination.
❑ Obtained from the plant in a similar manner and they be studied together with them.

24
Q

❑ A natural product of variable composition and of milky consistency making up the cytoplasm of special plant tissues consisting of laticiferous cells or vessels.

25
❑ The milky appearance is due to the _____ in a liquid dispersion medium with a very different refractive index.
COLLOIDAL SUSPENSION OF SMALL PARTICLES IN A LIQUID
26
These contain a large proportion of oxyacids, usually combining the properties of carboxylic acid and phenols.
RESIN ACIDS
27
Are soluble aqueous solutions of the alkalies usually soap like solutions or colloidal suspensions.
RESIN ACIDS
28
Metallic salts of Resin Acids are known as:
RESINATES
29
Examples of Resin Acids
▪ Abietic acid – Rosin or Colophony ▪ Aleuritic acid – Shellac ▪ Commiphoric acid – Myrrh ▪ Copaibic and Oxycopaibic acid – Copaiba ▪ Guaiaconic acid –Guaiac ▪ Primaric acid – Burgundy pitch and Frankincene ▪ Sandaracolic acid – Sandarac
30
❑ Are complex alcohols of high molecular weight
RESIN ALCOHOLS
31
It does not give such a reaction.
RESINOLS
32
It gives a tannin reaction with iron salts
RESINOTANNOLS
33
Examples of simple aromatic acids:
▪ Benzoic acid ▪ Salicylic acid ▪ Cinnamic acid ▪ Umbellic acid
34
Examples of Resin Alcohols
▪ Benzoresinol – Benzoin ▪ Storesinol – Storax ▪ Guaiacresinol – Guaiac
35
Examples of Resinotannols
▪ Aloeresinotannol –Aloe ▪ Peruresinotannol – Balsam of Peru ▪ Toluresinotannol – Balsam of Tolu ▪Ammoresinotannol and Galbaresinotannol – Ammoniac ▪ Siaresinotannol and Sumaresinotannol – Benzene
36
❑ Are complex neutral substances devoid of characteristic chemical properties.
RESENES
37
❑ They do not form salts or esters. ❑ Are insoluble in and resist by alkalies.
RESENES
38
Examples of Resenes
▪ Alban and Fluavil –Gutta percha ▪ Copalresene – Copal ▪ Dammaresene – Dammar ▪ Dracoresene – Dragon’s blood ▪ Olibanoresene – Olibanum
39
❑ Are complex mixtures yielding sugars and complex resin acids on hydrolysis.
GLUCORESINS/GLYCORESINS
40
Examples of Glucoresins
▪ Resins of Jalap ▪ Resins of Scammony
41
Resins are obtained by:
❖ Extracting the drug with alcohol and precipitating the resin with water. ❖Separating the oil from oleoresin by distillation ❖Heating the Plant part ❖Collecting Fossil resins ❖ Collecting the natural product that has exuded as oleoresins from the plant through natural or artificial punctures and from which the natural oils has partially evaporated into the atmosphere.
42
Extracting the drug with alcohol and precipitating the resin with water. Give examples.
▪ Jalap ▪ Ipomea ▪ Scammony ▪ Podophyllum
43
❖Separating the oil from oleoresin by distillation. Give examples
▪ Rosin –Turpentine ▪ Copaivic resin – Copaiba
44
❖Heating the Plant part. Give examples
▪ Guaiac resin –Guaiac wood
45
❖Collecting Fossil resins. Give examples.
▪ Copal ▪ Dammar ▪ Kauri
46
❖Collecting the natural product that has exuded as oleoresins from the plant through natural or artificial punctures and from which the natural oils has partially evaporated into the atmosphere. Examples
▪ Burgundy pitch ▪ Mastic ▪ Sandarac ▪ Dragon’s blood
47
Sources
• RESINS • CANNABIS • CHICO • CHINESE UMBRELLA TREE MELIA/ PARAISO • COMMON MILK HEDGE • DERRIS • GINGER • MANGO • MANGOSTEEN • MIMUSOPS • STICK TREE