Redox reactions Flashcards
What’s oxidation and what’s reduction
oxidation = loss of electrons, gain of oxygen
Reduction = gain of electron , removal of oxygen
When does oxidation and reduction happen ?
Example
at the same time .
Iron atoms are oxidised to Fe^2+ ions when they react with dilute acid Fe + big 2 H^+ -> Fe^2+ + h2
The iron atoms lose electrons. They’re oxidised by the hydrogen ions. Fe - big 2 e^-1 -> Fe^2+
The hydrogen ions gain electrons . They’re reduced by the iron atoms: Big 2 H ^+ + 2e^- -> H2
Displacement reactions are
redox reactions
1) displacement reactions involve one metal kicking one out of a compound
2) If you put a reaction metal into the solution of a dissolved metal compound, the reactive metal will replace the less reactive metal in the compound
Rule of displacement
A more reactive metal will displace a less reactive metal from its compound
Example of displacement reaction
If you put iron in a solution of CuSO4, the more reactive iron will ‘kick out’ the less reactive copper from the solution. You can end up with FeSO4 and copper metal
Fe(s) + CuSO4 ( aq) -> FeSO4( aq) + Cu (s)
In this reaction, iron loses 2 electrons to become 2+ ion = oxidised . Fe -> Fe^2+ +big 2 e^-
The copper ion gains these 2 electrons to become a copper atom = its reduced
Cu^2+ + big 2 e^- -> Cu
What occurs in a displacement reaction ?
always the metal ion that gain electrons and is reduced. Metal atom always loses electrons and is oxidised
In an ionic equation, only the
particles that react and the products they form are shown, For example, Mg(s) + Zn^2+ (aq) -> Mg^2+ (aq) + Zn (s)
This shows the displacement of zinc ions by Magnesium metal. The full equation
Mg(s) + Zncl2+ (aq) -> Mgcl2+ (aq) + Zn (s)
If you write out the equations, you can see all the ions and see chloride ions don’t change = spectator ion, they’re are of no interest so can be crossed out.
Mg(s) + Zn^2+ (aq) + big 2 Cl^- ( aq) -> Mg^2+ (aq) + big 2 Cl^- ( aq) + Zn (s)
Instead, the ionic equation of this displacement reaction just concentrates of the substances which are oxidised or reduced.