REDOX Flashcards
oxidation
donate e-
positive
reduction
accept e-
negative
oxidising agent
oxidises other species
gets reduced
reducing agent
reduced other species
gets oxidised
half reaction - oxidation + reduction
all metal act as reducing agent - donate e- and oxidised
measuring standard reduction potential
using electrochemical reduction potential
electrochemical reduction potential
and example
2 half cell connect via salt bridge and electric current flow between them
e.g. zinc in zinc solution
size of potential difference
is proportional to readiness of e- by reducing agent
determining standard reduction potential
uses H electrode = 0.00V
used to compare reducing potential of all species
standard H electrode
under standard conditions
H - bubbled in 1M H+ ions solution and metal is platinum - does not react and coat in Pt
increase SA and increase for H reaction therefore equilibrium set up faster
forward reaction in standard H electrode
reduction
standard redutcion
equilibrium position in half reaction
more -ve value = further left of half reaction at equilibrium
example of standard reduction - Mg and Zn
more heavy weight - to left than Zn therefore Mg - stronger reducing agent than Zn - forward reaction - Mg
Mg loses 2e- and Zn gains 2e-
strongest reducing agents
oxidised during REDOX