Rates of Reactions Flashcards
Define what is the rate of a chemical reaction
The rate of a chemical reaction is defined as the change in concentration of a reactant or product compared with the period of time taken for the change to occur.
Rate =
time taken for the change to occur
What is a measure of how quickly a reaction happens?
The rate, or speed, of a reaction is a measure of how quickly a reaction happens.
* Some reactions, like explosions, are very quick – they finish within seconds.
* Some reactions, like rusting, are very slow – they finish in months or years.
* Some reactions, like baking a cake, are somewhere in between – they finish in minutes or hours.
We can tell if a reaction is occurring quickly or slowly by…
monitoring a visible or measurable quantity.
For example:
* The change in mass in a given time if a gas is being given off
* The volume of gas given off in a certain amount of time
* The appearance of a precipitate
* The change in colour intensity, pressure, temperature or pH if these
are changing as the reaction proceeds
During any reaction, the concentration of reactants…
decreases at the same rate as the conc of products increasess
- In order for reactants to be converted to products,
effective collisions must occur
An effective collision requires that:
1) Particles must collide
2) Collisions must occur with an energy above the value of the
Activation Energy for the reaction
3) Collisions must occur with the correct orientation
define activation energy
Activation energy, in chemistry, is the minimum amount of energy that is required to activate atoms or molecules to a condition in which they can undergo chemical transformation.
The concentration of a reactant…
decreases with time
The concentration of a product…
increases with time
describe the rate curve
- At the beginning of the reaction, reactant concentration is the highest and the particles collide frequently, so rate is fast, there is a steep gradient to the curve.
- As reactants are used up, the concentrations decrease and particles collide less frequently; the reaction rat is slower and the gradient becomes less steep.
- Eventually when all reactant has been used up, no more collisions occur and gradient is flat (0).
Rate of reaction at a given time is equal to
the gradient of the tangent to the curve at that time.
list the property changes in the chemical reactions
- volume of gaseous product
- colour intensity
- amount of precipitate formed
- decrease in mass (if gas is evolved)