Diamond and graphite Flashcards
Allotropes
It is the different physical forms of the same element
List two allotropes of carbon
Diamond and graphite
What do allotropes refer to only
Elements only
How are the allotrophs diamond and graphite formed
diamond and graphite posses different structures and exist naturally in the earth and possibly formed via different conditions of temperature and pressure over the years. Many other elements also exhibit allotrophy.
Describe the structure of a diamond
-In a diamond each C is connected to 4 other elements. Each C is connected to a tetrahedral arrangement (4) which continues to build up a diant structure
- Diamond has a large network of covalent bonds
- Diamond is not slippery (used to cut through metal)
Describe the structure of graphite
-Each C is connected to 3 others. The atoms are arranged in flat hexagonal rings which form layers
- The layers are stacked on each other and held via weak van-der-waals forces
- Graphits has a large network of covalent bonds
- Each layer of graphite is called graphine
- when you write with a pencil with force, you break van-der-waals forces
- It is also used as a lubricant in factories
Melting points of diamond and graphite
Very high melting and boiling points as in order to melt them a large network of covalent bonds would be broken
Hardness of diamond
Due o the densly packed arrangement of atoms, it is one of the most hardest substances known to man
Hardness of graphite
Atoms are not as densly packed, the weak forces between the layers enable them to slide over each other, resulting in a “soft crystal” which feels slippery, therefore it can act as a lubricant
Conductivity of diamond
Diamond does not conduct electricity, the carbon atoms in diamond do not have any “free”electrons available to conduct an electric current
Conductivity of graphite
Is a good conductor of electricity, the fourth electron of each carbon atom becomes delocalized allowing it to move about in the crystal. The moving electrons carry electricity through the crystal, therefore it is used as electrodes during electrolysis
Shine of diamond
When light enters the structure it gets refracted many times which makes it shinier
Shine of graphite
The structure of graphite is sheet like and weak bonds do not refract any light which makes it look dull