POLYSACCHARIDES Flashcards

1
Q

```

~~~

general characteristic of polysaccharide

A

polymer chain

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2
Q

4 types of polymer chain

A

unbranched-chain homopolysaccharide
branched-chain homopolysaccharide
unbranched-chain heteropolysaccharide
branched-chain heteropolysaccharide

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3
Q

alterate name is glycan

A

polysaccharide

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4
Q

not sweet and don’t show
positive tests with Tollen’s
and Benedict’s solutions

A

polysaccharide

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5
Q

has limited water solubility

A

polysaccharide

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6
Q

2 kinds of Storage polysaccharides

A

– starch
– glycogen

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7
Q

2 types of Structural polysaccharides

A

– cellulose
– chitin

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8
Q

2 types of Acidic polysaccharides

A

– heparin
– hyaluronic acid

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9
Q

5 types of Homopolysaccharides

A

– starch
– glycogen
– cellulose
– chitin
– carageenan

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10
Q

4 types of Heteropolysaccharides

A

– hyaluronic acid
– heparin
– chondroitin sulfate
– alginic acid

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11
Q

the chief caloric distributor in the diet;

A

Starch

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12
Q

the reserve carbohydrates
for plants

A

Starch

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13
Q

2 kinds/parts of starch

A

amylose
amylopectin

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14
Q

has straight chain polymer;

A

Amylose

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15
Q

15 - 20% of the starch;

A

Amylose

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16
Q

water-soluble fraction;

A

Amylose

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17
Q

has 60 – 300 glucose units joined by α-1,4-

glycosidic bonds

A

Amylose

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18
Q

experimental evidence indicates that the molecule is actually
coiled like a spring and is not a straight chain of glucose units.

A

Amylose

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19
Q

When coiled in this fashion the molecule has just enough
room in its core to accommodate an iodine molecule.

A

Amylose

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20
Q

The characteristic ———— that starch gives when treated with
iodine is due to the formation of the amylose-I2 complex.

A

blue color

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21
Q

The iodine molecules align along the core
of the helical amylose, causing an
interaction that leads to the characteristic
color change of —-

A

(bluish-black)

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22
Q

has a branched chain polymer

A

Amylopectin

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23
Q

is 80 - 85 % of the starch

A

Amylopectin

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24
Q

the water-insoluble fraction of starch

A

Amylopectin

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25
composed of 300 – 6000 glucose units joined primarily by α-1,4- glucosidic bonds and occasionally by α -1,6- glucosidic bonds
Amylopectin
26
what bonds in amylopectin are responsible for branching which occurs about once every 25-30 units.
α -1,6 bonds
27
its α -1,6 bonds are responsible for branching which occurs about once every 25-30 units.
Amylopectin
28
the animal starch
Glycogen
29
glucose storage molecule of animals
Glycogen
30
stored in granules in liver and muscle cells
Glycogen
31
like amylopectin, is a nonlinear polymer of glucose units joined by  -1,4- and  -1,6-glycosidic bonds but has lower molecular weight
Glycogen
32
more highly branched structure
Glycogen
33
its branches are shorter
Glycogen
34
gives red-brown color with I2
Glycogen
35
a fibrous carbohydrate found in all plants where it serves as the structural component of the plant’s cell wall
cellulose
36
a linear polymer of glucose units joined by β-1,4- glucosidic bonds
cellulose
37
linear nature of chains allows close packing into fibers, making it difficult for solvent molecules to pull the chains apart, thus cellulose is inert towards most solvents
cellulose
38
is ~95% cellulose
Cotton
39
is ~50% cellulose
wood
40
It serves as dietary fiber in food-- readily absorbs water and results in softer stools
cellulose
41
20 - 35 g of dietary fiber is desired everyday
cellulose
42
composed of glucose monomers linked by β(1→4) glycosidic bonds.
cellulose
43
yields D-glucose upon hydrolysis yet man & the carnivorous animals can’t utilize it as a source of glucose.
cellulose
44
human‘s digestive juices lack the enzyme
cellulase
45
that hydrolyze the glucosidic linkages.
cellulase
46
ruminants (cows, goats) and termites have, within their digestive tracts, microorganisms that produce
cellulase
47
has a similar to cellulose in both function and structure
Chitin
48
polymer of N-acetyl-D- glucosamine bound by β-1 4 glycosidic linkages
Chitin
49
(has a linear extended structure like cellulose)
Chitin
50
Function is to give rigidity to the exoskeletons of crabs, lobsters, shrimp, insects, and other arthropods
Chitin
51
itself is inert and practically insoluble in most solvents.
Chitin
52
can be prepared by simple alkali- catalyzed deacylation.
chitosan
53
are commercially used as films, fibers, surface coatings and ultrafiltration membranes
Chitosan derivatives
54
B-(1,4)-N-Acetyl-D-glucosamine
Chitin
55
occurs as hydrocolloid extracted from selected species of red algae
Carageenan
56
locally obtained from Eucheuma striatum, Eucheuma spinosum and Acanthapora
Carageenan
57
sulphated polysaccharides, consisting of polymers of sulphated D-galactopyranose bonded through alternating α- 1,3 and β-1,4 glycosidic linkages
Carageenan
58
widely used in food industry
Carageenan
59
polymers of sulphated D-galactopyranose bonded through alternating α- 1,3 and β-1,4 glycosidic linkages
Carageenan
60
its gelling property is used in enhancing the texture of various dairy products and in preventing oiling off in caramel and toffee during hot weather
Carageenan
61
also serve as coating to retard moisture loss from foods and fresh produce like fruits and vegetables
Carageenan
62
The OSO3 − group is known as a
sulfate ester group.
63
It consists of a sulfur atom double-bonded to two oxygen atoms and single-bonded to one oxygen atom, which in turn is bonded to a carbon atom in the sugar ring.
sulfate ester group
64
repeating unit is a disaccharide composed of β-D-glucouronic acid and N-acetyl-D-glucosamine in a β-(1,3)-linkage.
Hyaluronic acid
65
β-D-glucouronic acid and N-acetyl-D-glucosamine in a β-(1,3)-linkage.
Hyaluronic acid
66
each disaccharide is attached to the next by β-(1,4)-linkage
Hyaluronic acid
67
alternating β-(1,3) and β-(1,4)- linkages
Hyaluronic acid
68
highly viscous
Hyaluronic acid
69
serve as lubricants in the fluid of joints and part of vitreous humor of the eye
Hyaluronic acid
70
when some insects sting, they inject an enzyme called
hyaluronidase
71
an enzyme that breaks hyaluronic acid linkages and facilitates the spread of the venom
hyaluronidase
72
reduces the viscosity of hyaluronic acid, making it useful in medical and cosmetic applications.
Hyaluronidase
73
these injections improve the absorption of medications. Cosmetically, it degrades hyaluronic acid following dermal filler treatments.
hyaluronidase
74
consists of repeating units of D- glucuronic acid and D- glucosamine
Heparin
75
an anticoagulant in blood that inhibits blood clot formation
Heparin
76
used in open-heart surgery
Heparin
77
locally extracted from Sargassum seaweeds
Alginic acid
78
consist of repeating units of β- 1,4 bonded mannuronic and α- 1,4 bonded L-guluronic acid; cell wall material
Alginic acid
79
β- 1,4 bonded mannuronic and α- 1,4 bonded L-guluronic acid
Alginic acid
80
serves as base coatings in meats and fish which reduces moisture loss and fat absorption
Alginic acid
81
consists of repeating units of D- glucuronic acid-D-glucosamine sulfate
Chondroitin sulfate
82
D- glucuronic acid-D-glucosamine sulfate
Chondroitin sulfate
83
structural role in cartilage, bone, and cornea of the eye
Chondroitin sulfate
84
A developing concern about intake of carbohydrates involves how fast the given dietary carbohydrates are broken down to glucose within the human body
Glycemic Foods
85
refers to: – how quickly carbohydrates are digested – how high blood glucose rises – how quickly blood glucose levels return to normal
Glycemic index
86
has been developed for rating foods
Glycemic index (GI)
87
Low-GI foods are
desirable
88
is a lipid molecule that has one or more carbohydrate (or carbohydrate derivative) units covalently bonded to it.
glycolipid
89
is a protein molecule that has one or more carbohydrate (or carbohydrate derivative) units covalently bonded to
glycoprotein
90
Such carbohydrate complexes are very important in cellular functions such as cell-cell recognition, cell adhesion and cellular communication.
Glycolipids and Glycoproteins
91
in the diet aids in the formation of bulk in the intestinal tract, which increases the absorption of water along the tract.
Fiber
92
as it reaches the gut, is intact in structure where they form a meshwork
Dietary fiber
93
2 examples
gastrin and cholecystokinin
94
Lack of dietary fiber may also lead to
overnutrition
95
can be trapped in the meshwork reducing the concentration of blood -----
Cholesterol