Structure and Classification of Lipids Flashcards
An organic compound found in living organisms that is insoluble
(or only sparingly soluble) in water but soluble in non-polar
organic solvents.
Lipids
do not have a common structural
features that serves as the basis for defining such compounds.
lipids
two methods of classification of lipids
– Biochemical function
– Saponification
(hydrolysis under basic conditions)
Saponification
6 categories of lipids
based on their biochemical function:
– Energy-storage lipids
– Membrane lipids
– Emulsification lipids
– Chemical messenger lipids
– Protective-coating lipids
– Transport lipids
a type of Energy-storage lipids
triacylglycerols
3 types of Membrane lipids
phospholipids, sphingoglycolipids, and cholesterol
a type of Emulsification lipids
bile acids
2 types of Chemical messenger lipids
steroid hormones and eicosanoids
a type of Protective-coating lipids
biological waxes
a type of Transport lipids
lipoproteins
Hydrolysis reaction that occurs in a basic
solution.
Saponification/Saponification reaction:
Based on saponification reactions lipids are divided into two categories:
Saponifiable lipids
Nonsaponifiable lipids
5 types of Saponifiable lipids
triacylglycerols
phospholipids,
sphingoglycolipids,
cholesterol
biological waxes
3 types of Nonsaponifiable lipids
bile acids
steroid hormones
eicosanoids
they exhibit structural
diversity
Lipids
Some are esters, some are amides, and some are alcohols (acyclic and cyclic) and some are polycyclic.
Lipids
are naturally occurring monocarboxylic acids
Fatty acids
3 types of carbon atom chain length
– Long chain fatty acids: C12 - C26
– Medium chain fatty acids: C6 - C11
– Short-chain fatty acids: C4- C5
2 types of fatty acids
Saturated
Unsaturated
when all C-C bonds are single bonds
Saturated
2 types of Unsaturated fatty acids
Monounsaturated
Polyunsaturated:
an unsaturated fatty acid with one C=C bond
Monounsaturated:
an unsaturated fatty acids with 2 or more C=C bonds present - up to six double bonds are present in fatty acids
Polyunsaturated: