part 2: orbitals/electron configurations Flashcards
Pauli Exclusion Principle:
Each electron in an atom has a unique set
of four quantum numbers n, l, m l and m s
Maximum of two electrons per orbital!
Aufbau Principle:
electrons occupy the lowest energy level first
Hund’s Rule
If more than one orbital in a sublevel is available, electrons
will fill empty orbitals in that sublevel first with the same spin orientation
Near-Degenerate Orbitals:
orbitals with nearly the same energy.
Because the orbitals are so close in energy, it is
possible for an electron to be promoted to the higher energy orbital.
isoelectronic
Ions with the same number of electrons
Different nuclear charges
Diamagnetic
Paramagnetic
if they are repelled by a strong magnet. The
ions or atoms have paired electrons.
if they are attracted to a magnet, align itself
in a magnetic field. the ions or atoms have unpaired
electrons.
Electron Affinity
The energy change when an electron is added to an atom.
* For the main group elements, the EA tends to become
more negative from left to right across a row of the
periodic table.
Atomic Radii
Distance between the nucleus and outer surface of the
largest orbital
True or false
E is always positive
true
removing electron takes energy