Molecular Composition Flashcards

1
Q

What elements make up 99% of the weight of all living matter

A

CHNOPS

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2
Q

Most important organic molecules

A

-Carbohydrates (consist of sugar chains)
-lipids (fatty acids)
-proteins (composed of amino acids)
-nucleic acids (DNA and RNA)

Contain C and H

Proteins gave N and S

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3
Q

Carbohydrates

Monosaccharides
Disaccharides
Polysaccharides

A

1-glucose, fructose, ribose
-consist of a single sugar subunit
-building blocks, primary sources of energy

2-sucrose, maltose, lactose
-consist of two sugar subunits linked covalently
-energy transfer, transport

Many-cellulose (glycogen, chitin) and starch
-many sugar subunits linked together covalently
-storage, structure

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4
Q

Monosaccharides in a formula

A

(CH20)n

n can be as small as 3 or as large as 7

Proportions gave rise to the term carbohydrate meaning carbon with water added.

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5
Q

What group do monosaccharides have

A

Carbonyl group because as ring is formed, carbonyl is turned to a hydroxyl group

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6
Q

Sugars are often transported in plants and other organisms as ____

A

Disaccharides

Specifically sucrose made from glucose and fructose is the form in which sugar is transported in most plants

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7
Q

Dehydration synthesis/ condensation reaction

A

Synthesis of a disaccharide from two monosaccharide molecules in which a water molecule is removed and a new bond is formed between the two monosaccharides

Requires energy input

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8
Q

Hydrolysis

A

Reverse condensation reaction in which water is added and the molecules are split.

Energy yielding

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9
Q

Starch

A

Primary storage polysaccharide in plants consisting of chains of glucose molecules.

Two forms of starch:
-amylose: unbranched molecule
-amylopectin: branched molecule

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10
Q

Glycogen

A

Most coming storage polysaccharide in prokaryotes, fungi and animals made up of chains of glucose molecules. Resembles amylopectin but it more branches

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11
Q

What must happen to polysaccharides to be used as energy sources and transported through living systems?

A

Hydrolysis to monosaccharides and disaccharides

Plants break down starch reserves when needing to grow and develop

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12
Q

Cellulose

What can hydrolysis cellulose?

A

A polymer composed of monomers of glucose.

Only some microorganisms, certain prokaryotes, protozoa, fungi and few animals (who have these microorganisms in their stomachs aka cows)

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13
Q

Difference in starch, glycogen and cellulose structure

A

Starch and glycogen are made up entirely of alpha-glucose subunits

Cellulose entirely of beta-glucose subunits. Makes cellulose impervious to enzymes to break down starch and glycogen. Once in plant cell wall, no longer useable by the plant as energy source.

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14
Q

Chitin

A

Structural polysaccharide and principal component of fungal cell walls/ hard outer exoskeleton of insects and crustaceans

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15
Q

Cutin and suberin

A

Lipids in plant cell walls that form a matrix in which waxes are embedded. The waxes and lipids form a barrier to prevent water/ molecule loss

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16
Q

Epicuticular wax

A

The covering over the cuticle of plants
-wax off apples
-cuticular wax is made from cutin

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17
Q

Suberin is a major component of the walls of _____ cells

A

Cork

Form outermost layer of bark of woody stems and roots

Alternating light and dark layered band appearance

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18
Q

Steroids function in plants

A

-sterols make cell membranes to stabilize phospholipid tails
-hormones (some plants make estrogen)

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19
Q

How do plants use proteins

A

In seeds, 40% of dry weight of seeds is protein. Function as storage of amino acids to be used by embryo when it resumes growth upon germination of the seed.

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20
Q

What are nucleotides made up of

A

Phosphate group, 5 carbon sugar and a nitrogenous base

Sugar can be ribose or deoxyribose

Nitrogenous base can be adenine, cysteine, guanine, thiamine and uracil

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21
Q

Principal energy carrier for life

A

Adenosine Triphosphate

-3 phosphates bonds are weak and can be broken up for energy release

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22
Q

Primary and secondary metabolites

A

Molecules that are found in all plant cells and are excess age for the life of the plant-sugars, amino acids, proteins and nuclei acids

Restricted in their distribution, both within the plant and along the different species of plants-chemical signals, defence, pathogens, protection from radiation of sun, aid in pollen and seed dispersal. Stored in vacuoles normally.

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23
Q

Phytoalexins

A

Antimicrobial compounds produced only after wounding or after attack by bacteria or fungi

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24
Q

3 major types of secondary plant compounds

A

Alkaloids- pharmalogical or medicinal affects: morphine, caffeine, nicotine, cocaine, atropine (eye dilation)

Terpenoids- in all plants, composed of isoprenes (gas emitted in significant quantities by leaves especially in heat): essential oils, taxol (anti cancer), rubber, cardiac glycosides (heart attack, in milk weed to protect caterpillars/butterflies)

Phenolics- in all plant parts in all plants; flavonoids(can inhibit genetic response, protect from UV), tannins (bitter repellant) , lignins (in cell wall, strength and water proof) and salicylic acid (aspirin, esssential in SAR)

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25
Q

SAR

A

Systematic acquired resistance

In Response to a localized attack by pathogenic bacteria, fungi, or viruses to protect plant.

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26
Q

Function of lipids in plants

A

-energy storage in fruits and seeds
-cell membrane component
-protection (cutin, suberin and waxes)
-steroids (cell membrane and hormones)

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27
Q

Function of proteins in plants

A

Structural and catalytic functions

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28
Q

Primary metabolism is composed of

Most of the dry weight of organisms is made up of four types of organic molecules

A

Carbs
Lipids
Proteins
Nucleic acids

29
Q

Most of the dry weight of organisms is made up of four types of organic molecules

A
30
Q

Organic molecule

A

Consists of carbon

Binds to hydrogen

31
Q

Alpha glucose and beta fructose =

A

OH on right bottom

OH on right upper side

Fructose

32
Q

Cellulose is not available as a

A

Energy source

33
Q

Is alpha or beta binds easier to digest

A

Alpha

Takes different enzymes

34
Q

Amylose

A

Linear chain of repeated alpha-glucose monomers

35
Q

Amylopectin

A

Branched chain of repeated alpha-glucose monomers

36
Q

Cell walls have no _____ which makes them less fluid and instead more rigid

A

Cholesterol

37
Q

Lipids

A

Long C-H chains that are hydrophobic

38
Q

Triglycerides

A

Fats and oils used in energy storage

39
Q

Phospholipids

A

Lipids used as main component of cellular membranes

40
Q

Fatty acid vs phospholipid structure

A

Fatty acid- glycerol attached to 3 fatty acids

Phospholipid- phosphate group attached to a glycerol which 2 fatty acid tails

41
Q

Suberin and lignin structural appearance

A

Suberin has verticals zig zags

Lignin has computer chip look

42
Q

Sterol

A

Steroid with OH in carbon 3 position

43
Q

Protein dry weight in organism and plants

A

Very abundant component of organisms
~50% of dry weight, but not in plants because of high cellulose content

44
Q

What type of bond do proteins have

A

Peptide bonds which are covalent

45
Q

Protein structure types

A

Primary- sequence of amino acids

Secondary- chains fold and interact in chain into alpha helix or beta pleated sheet with H bonds

Tertiary- more folding into solid structure

Quaternary-different subunits of tertiary structures together (hemoglobin)

46
Q

Nucleic acids

A

Consists of long chains of nucleotides

ATP, ADP, AMP

47
Q

Nucleotides

A

Phosphate group, pentode and nitrogen base

Information molecules

48
Q

AMP is not in energy transport, but acts as a

A

Secondary messenger

49
Q

Types of RNA

A

mRNA, tRNA, rRNA

50
Q

Which nitrogenous bases go together

A

Adenine, thymine and uracil

Guanine, cytosine

51
Q

Purines
Pyrimidines

A

Adenine, guanine - two ring

Thymine, cytosine, uracil -one ring

52
Q

Primary metabolites

A

Molecules found in all plant cells, necessary for cell functions and plant life
-respiration and photosynthesis

53
Q

Secondary metabolites

A

Organic molecules of restricted distribution among species and within the plant body
-stored primarily in vacuoles
-chemical signals invoked in response s to biotic or abiotic cues
-anti-herbivore, anti-pathogen, allelochemicals

54
Q

Allelochemicals

A

Organic Chemicals released from roots that make it difficult for other plants to grow around it

55
Q

Major classes of secondary metabolites

A

Alkaloids
Terpenoids
Phenolics
Phytoalexins

56
Q

Phytoalexins

A

-antimicrobial
-produced only after wounding or infection
-different chemical classes: terpenoids, glycosteroids, alkaloids

57
Q

Alkaloids

A

Nitrogenous compounds important for pharmacological/ medicinal, physiological, psychological effects
-10,000 different alkaloids known

58
Q

Alkaloids examples

A

-caffeine
-cocaine
-nicotine
-morphine
-strychnine
-quinine : malaria treatment
-ephedrine : cough treatment
-atropine

59
Q

Can caffeine be produced in more than 1 way?

A

Yes, 5 biochemical pathways to produce caffeine in plants

Result of convergent evolution showing that caffeine is used as a defence against herbivores and insects

60
Q

Terpenoids structure

A

-composed of isoprene units (C5H8)
-largest class of secondary metabolites (22,000)

-monoterpenoids (C10)
-sesquiterpenoids (C15)
-diterpenoids (C20)

61
Q

Terpenoids examples

A

-essential oils (pollinator attraction)
-taxol
-rubber

62
Q

Rubber structure

A

-Largest terpenoid
-400-100,000 isoprene units

63
Q

Terpenoids functions

A

-photosynthetic pigments (carotenoids)
-hormones (GA-growth, ABA-senescence)
-membrane structure (sterols)

64
Q

What terpenoids is a compound in milkweed?

A

Cardiac glycosides

65
Q

Phenolics structure

A

-broad range of compounds with a hydroxyl group (-OH) attached to aromatic ring
-present in most plants and plant parts

66
Q

Examples of Phenolics

A

-Tannins
-Flavonoids
-Lignins
-salicylic acid

67
Q

Flavonoids

A

Phenolic compounds

-anthocyaninin , flavones and flavonols
-co pigmentation if anthocyanins and flavones joined through complexes with metal ions

68
Q

Where are tannins located in cells

A

Vacuoles

69
Q

Purpose of salicylic acid

A

Pathogen defence