Midterm - Carbohydrates Flashcards
stereoisomers
same molecular formula and sequence but differ in 3D space due to chiral carbon atoms
enantiomer
mirror image
diastereomers
not a mirror
D - configuration
last OH group on the right
L-configuration
last OH group on the left
how to determine the number of stereoisomers for a molecule
2^n
where n = # chiral carbons
why are D-monosaccharides nutritionally important
digestive enzymes are stereospecific for D sugars
hemiacetal
made from aldose
hemiketal
made from ketose
what is the most common oligosaccharide
disaccharides
what are two types of polysaccharides
homopolysaccharides
heteropolysaccharides
which is more abundant in food
homopolysaccharides
what polysaccharide is rich in plants
starch (amylose, amylopectin)
what polysaccharide is rich in animal
glycogen
what kind of fibre is cellulose
both a dietary and a functional fibre
what is cellulose
homopolysaccharide of B-1,4 glucose units
health benefits of fibre
maintains function and health of gut
decreases constipation
increases satiety
3 fates of glucose in a cell
- enters glycogenesis for energy storage
- enters glycolysis for energy production
- enters hexose monophosphate shunt to generate precursors for biogenesis
what does the use of glucose depend on
the cell and its requirements at the time
glycogenin
enzyme that serves as a scaffold on which to attach glucose molecules to build glycogen (primer)
how many glucose molecules can be contained in a single glycogen structure
30,000+
what do insulin and glucagon work to maintain
blood glucose homeostasis
when does the cori cycle occur
anaerobic state
what is the hexose monophosphate shunt important for
NADH production and ribose synthesis