Midterm - Carbohydrates Flashcards

1
Q

stereoisomers

A

same molecular formula and sequence but differ in 3D space due to chiral carbon atoms

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2
Q

enantiomer

A

mirror image

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3
Q

diastereomers

A

not a mirror

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4
Q

D - configuration

A

last OH group on the right

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5
Q

L-configuration

A

last OH group on the left

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6
Q

how to determine the number of stereoisomers for a molecule

A

2^n
where n = # chiral carbons

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7
Q

why are D-monosaccharides nutritionally important

A

digestive enzymes are stereospecific for D sugars

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8
Q

hemiacetal

A

made from aldose

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9
Q

hemiketal

A

made from ketose

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10
Q

what is the most common oligosaccharide

A

disaccharides

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11
Q

what are two types of polysaccharides

A

homopolysaccharides
heteropolysaccharides

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12
Q

which is more abundant in food

A

homopolysaccharides

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13
Q

what polysaccharide is rich in plants

A

starch (amylose, amylopectin)

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14
Q

what polysaccharide is rich in animal

A

glycogen

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15
Q

what kind of fibre is cellulose

A

both a dietary and a functional fibre

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16
Q

what is cellulose

A

homopolysaccharide of B-1,4 glucose units

17
Q

health benefits of fibre

A

maintains function and health of gut
decreases constipation
increases satiety

18
Q

3 fates of glucose in a cell

A
  1. enters glycogenesis for energy storage
  2. enters glycolysis for energy production
  3. enters hexose monophosphate shunt to generate precursors for biogenesis
19
Q

what does the use of glucose depend on

A

the cell and its requirements at the time

20
Q

glycogenin

A

enzyme that serves as a scaffold on which to attach glucose molecules to build glycogen (primer)

21
Q

how many glucose molecules can be contained in a single glycogen structure

22
Q

what do insulin and glucagon work to maintain

A

blood glucose homeostasis

23
Q

when does the cori cycle occur

A

anaerobic state

24
Q

what is the hexose monophosphate shunt important for

A

NADH production and ribose synthesis

25
where does the hexose monophosphate shunt occur
cytoplasm
26
what is the hexose monophosphate shunt used to generate
NADPH and precursors for nucleotide synthesis
27
what is the total amount of energy from 1 molecule of glucose
38 ATP
28
when is gluconeogensis active
when glucose is needed in the body
29
what are nearly all monosaccharides taken up by
enterocytes
30
what is the transport of glucose to galactose from lumen to blood dependent on
basolateral Na-K ATPase activity
31
what is fructose taken up by
facilitated transport
32
how do glucose, galactose and fructose all enter blood
via GLUT2
33
what is the primary source of energy for cells
glucose
34
what do carbs spare
protein (prevents protein breakdown)
35
what do carbs prevent
ketosis
36
what occurs when carbs are limited
fats get broken down for energy, producing ketone bodies and causing blood to become acidic